| Identification | Back Directory | [Name]
(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE | [CAS]
149341-33-3 | [Synonyms]
R-QUINAR
(S)-QUINAP
(R)-QUINAP
(S)-(-)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE
(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE
(S)-(-)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline,98%
(S)-(-)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline S-QUINAP
(S)-(-)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline >=95.0% (qNMR) | [Molecular Formula]
C31H22NP | [MDL Number]
MFCD01073773 | [MOL File]
149341-33-3.mol | [Molecular Weight]
439.49 |
| Chemical Properties | Back Directory | [Appearance]
white to off-white crystalline powder | [Melting point ]
220-230 °C
| [Boiling point ]
588.1±38.0 °C(Predicted) | [storage temp. ]
2-8°C | [form ]
Crystalline Powder | [pka]
4.45±0.30(Predicted) | [color ]
White to off-white | [BRN ]
6664856 | [InChI]
1S/C31H22NP/c1-3-13-25(14-4-1)33(26-15-5-2-6-16-26)29-20-19-23-11-7-9-17-27(23)30(29)31-28-18-10-8-12-24(28)21-22-32-31/h1-22H | [InChIKey]
YMJAIEYASUCCMJ-UHFFFAOYSA-N |
| Hazard Information | Back Directory | [Chemical Properties]
white to off-white crystalline powder | [Uses]
(S)-QUINAP can be used as a ligand:
- In the asymmetric hydrosilylation of alkyl and α, β-unsaturated ketones in the presence of Fe(OAc)2.??????
- For the synthesis of chiral organoboron compounds by copper-catalyzed β-borylation of α,β-unsaturated esters.
[Ir(cod)Cl]2 treated with ligand (S)-QUINAP forms an iridium complex. This complex is used as a catalyst for the enantioselective hydrogenation of olefins. (S)-QUINAP–Rh complex can be employed as a catalyst in enantioselective hydroboration/oxidation of perfluoroalkenes. | [General Description]
(S)-QUINAP is a bidentate ligand used in catalytic asymmetric hydroboration, hydrogenation, oxidation, and allylic alkylation reactions. |
|
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Energy Chemical
|
| Tel: |
021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Merck KGaA
|
| Tel: |
21-20338288 |
| Website: |
www.sigmaaldrich.cn |
|