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149646-83-3

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149646-83-3 Structure

149646-83-3 Structure
IdentificationBack Directory
[Name]

6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN
[CAS]

149646-83-3
[Synonyms]

(R,R)-CHIRAPHITE
6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN
(+)-6,6-([(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin]
(+)-6,6'-{[(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin],min.95%(R,R)-Chiraphite
[Molecular Formula]

C49H66O10P2
[MDL Number]

MFCD06798296
[MOL File]

149646-83-3.mol
[Molecular Weight]

876.99
Chemical PropertiesBack Directory
[alpha ]

+35.4° (c 1.0, CH2Cl2)
[Boiling point ]

816.6±65.0 °C(Predicted)
[storage temp. ]

2-8°C, protect from light, stored under nitrogen
[form ]

Powder
[color ]

off-white
[Sensitive ]

air sensitive, moisture sensitive
[InChIKey]

XMUZNZWRMNWOHX-FQLXRVMXSA-N
[SMILES]

[C@@H](OP1OC2=C(C(C)(C)C)C=C(OC)C=C2C2=CC(OC)=CC(C(C)(C)C)=C2O1)(C)C[C@H](OP1OC2=C(C(C)(C)C)C=C(OC)C=C2C2=CC(OC)=CC(C(C)(C)C)=C2O1)C
[CAS DataBase Reference]

149646-83-3
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
Questions And AnswerBack Directory
[Reaction]

Useful catalyst for the asymmetric hydroformylation of olefins under mild conditions. High enantioand regioselectivities have been demonstrated for several prochiral vinylarenes, and a wide variety of functional groups can be tolerated. Reactions of 149646-83-3
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