| Identification | Back Directory | [Name]
Chloro(2-methylphenyl)[1,1'-bis(diphenylphosphino)ferrocene]nickel (II) | [CAS]
1501945-23-8 | [Synonyms]
chloro(2-methylphenyl)[1,1`-bis(diphenylphosphino)ferrocene]nickel
CHLORO(2-METHYLPHENYL)[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]NICKEL(II),98%
(2-methylphenyl)[1,1'-bis(diphenylphosphino)ferrocene] Nickel (II) chloride
Chloro(2-methylphenyl)[1,1'-bis(diphenylphosphino)ferrocene]nickel (II), 98% | [Molecular Formula]
C41H29ClFeNiP2 | [MDL Number]
MFCD28411349 | [MOL File]
1501945-23-8.mol | [Molecular Weight]
733.62 |
| Chemical Properties | Back Directory | [Melting point ]
173 °C | [storage temp. ]
2-8°C | [form ]
Powder | [color ]
yellow | [Sensitive ]
air sensitive | [InChI]
InChI=1S/2C17H11P.C7H7.ClH.Fe.Ni/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-7-5-3-2-4-6-7;;;/h2*1-6,9-12,18H;2-5H,1H3;1H;;/q;;-1;;+2;/p-1 | [InChIKey]
BNPFTYORGXHTBI-UHFFFAOYSA-M | [SMILES]
[Cl-][Ni+2]1([C-]2=CC=CC=C2C)P(C2C=CC=CC=2)(C2C=CC=CC=2)[C-]23C4=C5C6=C2[Fe+2]27893456C3C2=C7[C-]8(C9=3)P1(C1C=CC=CC=1)C1C=CC=CC=1 |
| Hazard Information | Back Directory | [Uses]
(dppf)Ni(o-tolyl)Cl is an air stable reagent. Its crystal structure has been investigated by X-ray studies. (dppf)Ni(o-tolyl)Cl can be prepared from (Ph3P)2Ni(o-tolyl)Cl. It is widely employed as a precatalyst for various C-N bond formation reactions. Efficacy of (dppf)Ni(o-tolyl)Cl as a precatalyst for the amination of 4-n-butylchlorobenzene with morpholine under various optimized reaction conditions has been investigated. | [General Description]
(dppf)Ni(o-tolyl)Cl is an air stable reagent. Its crystal structure has been investigated by X-ray studies. (dppf)Ni(o-tolyl)Cl can be prepared from (Ph3P)2Ni(o-tolyl)Cl. It is widely employed as a precatalyst for various C-N bond formation reactions. Efficacy of (dppf)Ni(o-tolyl)Cl as a precatalyst for the amination of 4-n-butylchlorobenzene with morpholine under various optimized reaction conditions has been investigated. | [reaction suitability]
core: nickel
reaction type: Cross Couplings
reagent type: catalyst |
|
| Company Name: |
Shanghai UCHEM Inc.
|
| Tel: |
18939844854 |
| Website: |
www.chemicalbook.com/supplier/23967788/ |
| Company Name: |
Merck KGaA
|
| Tel: |
21-20338288 |
| Website: |
www.sigmaaldrich.cn |
|