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1504-06-9

1504-06-9 Structure

1504-06-9 Structure
IdentificationBack Directory
[Name]

3-METHYLOXINDOLE 96
[CAS]

1504-06-9
[Synonyms]

3-Methyloxyindole
3-Methyl-2-oxindole
3-METHYLOXINDOLE 96%
3-METHYLOXINDOLE 96
3-Methyl-2-indolinone
3-methylindolin-2-one
3-Methyl-2-oxindole 96%
3-METHYLOXINDOLE 96 USP/EP/BP
3-Methyl-1,3-dihydro-indol-2-one
1,3-Dihydro-3-Methyl-2H-indol-2-one
3-methyl-2,3-dihydro-1H-indol-2-one
3-Methyl-2-oxindole,3-Methyloxindole
3-Methyloxyindole in stock Factory
2H-Indol-2-one, 1,3-dihydro-3-Methyl-
(R,S)-3-Methyl-1,3-dihydro-indol-2-one
[EINECS(EC#)]

1533716-785-6
[Molecular Formula]

C9H9NO
[MDL Number]

MFCD04037370
[MOL File]

1504-06-9.mol
[Molecular Weight]

147.174
Chemical PropertiesBack Directory
[Melting point ]

117-121 °C(lit.)
[Boiling point ]

279.3±29.0 °C(Predicted)
[density ]

1.123±0.06 g/cm3(Predicted)
[storage temp. ]

Sealed in dry,Room Temperature
[solubility ]

Chloroform (Slightly), Ethanol (Slightly), Methanol (Slightly)
[form ]

Solid
[pka]

14.81±0.40(Predicted)
[color ]

Light Beige to Beige
[Water Solubility ]

Insoluble in water.
[CAS DataBase Reference]

1504-06-9
Hazard InformationBack Directory
[Uses]

• ;Reactant for enantioselective α-amination reactions1• ;Reactant for aldol reaction with glyoxal derivatives2• ;Reactant for amine thiourea catalyzed conjugate addition to α,β-unsaturated aldehydes3• ;Reactant for O-acetylation reactions4• ;Reactant for preparation of a disubstituted oxoindole by using rhodium-catalyzed cyclopropanation/ring-opening reactions5
[Uses]

3-Methylindole metabolite.
[Definition]

ChEBI: 3-methyloxindole is a member of the class of oxindoles that is oxindole (1,3-dihydro-2H-indol-2-one) in which one of the hydrogens at position 3 has been replaced by a methyl group. It is a member of oxindoles and a methylindole.
[General Description]

3-Methyl-2-oxindole (MOI) is a 3-substituted-2-oxindole. It is reported to be formed during the oxidation of indole-3-acetic acid in the presence of FeII under aerobic conditions. MOI undergoes asymmetric anti-Mannich-type reaction with N-tosyl aryl aldimines in the presence of alkaloid cinchona derivatives to form anti-3,3-disubsituted 2-oxindole derivatives. It also undergoes asymmetric hydroxyamination with nitrosoarenes to form N-nitroso aldol products.
[storage]

Store at -20°C
Safety DataBack Directory
[WGK Germany ]

3
[HS Code ]

2933790090
Spectrum DetailBack Directory
[Spectrum Detail]

3-METHYLOXINDOLE 96(1504-06-9)1HNMR
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