ChemicalBook--->CAS DataBase List--->1504-06-9

1504-06-9

1504-06-9 Structure

1504-06-9 Structure
IdentificationBack Directory
[Name]

3-METHYLOXINDOLE 96
[CAS]

1504-06-9
[Synonyms]

3-Methyloxyindole
3-Methyl-2-oxindole
3-METHYLOXINDOLE 96%
3-METHYLOXINDOLE 96
3-Methyl-2-indolinone
3-methylindolin-2-one
3-Methyl-2-oxindole 96%
3-METHYLOXINDOLE 96 USP/EP/BP
3-Methyl-1,3-dihydro-indol-2-one
1,3-Dihydro-3-Methyl-2H-indol-2-one
3-methyl-2,3-dihydro-1H-indol-2-one
3-Methyl-2-oxindole,3-Methyloxindole
3-Methyloxyindole in stock Factory
2H-Indol-2-one, 1,3-dihydro-3-Methyl-
(R,S)-3-Methyl-1,3-dihydro-indol-2-one
[EINECS(EC#)]

1533716-785-6
[Molecular Formula]

C9H9NO
[MDL Number]

MFCD04037370
[MOL File]

1504-06-9.mol
[Molecular Weight]

147.174
Chemical PropertiesBack Directory
[Melting point ]

117-121 °C(lit.)
[Boiling point ]

279.3±29.0 °C(Predicted)
[density ]

1.123±0.06 g/cm3(Predicted)
[storage temp. ]

Sealed in dry,Room Temperature
[solubility ]

Chloroform (Slightly), Ethanol (Slightly), Methanol (Slightly)
[form ]

Solid
[pka]

14.81±0.40(Predicted)
[color ]

Light Beige to Beige
[Water Solubility ]

Insoluble in water.
[CAS DataBase Reference]

1504-06-9
Hazard InformationBack Directory
[Uses]

• ;Reactant for enantioselective α-amination reactions1• ;Reactant for aldol reaction with glyoxal derivatives2• ;Reactant for amine thiourea catalyzed conjugate addition to α,β-unsaturated aldehydes3• ;Reactant for O-acetylation reactions4• ;Reactant for preparation of a disubstituted oxoindole by using rhodium-catalyzed cyclopropanation/ring-opening reactions5
[Uses]

3-Methylindole metabolite.
[Definition]

ChEBI: 3-methyloxindole is a member of the class of oxindoles that is oxindole (1,3-dihydro-2H-indol-2-one) in which one of the hydrogens at position 3 has been replaced by a methyl group. It is a member of oxindoles and a methylindole.
[General Description]

3-Methyl-2-oxindole (MOI) is a 3-substituted-2-oxindole. It is reported to be formed during the oxidation of indole-3-acetic acid in the presence of FeII under aerobic conditions. MOI undergoes asymmetric anti-Mannich-type reaction with N-tosyl aryl aldimines in the presence of alkaloid cinchona derivatives to form anti-3,3-disubsituted 2-oxindole derivatives. It also undergoes asymmetric hydroxyamination with nitrosoarenes to form N-nitroso aldol products.
[Synthesis]

3-Methylhydroxyindole can be prepared from α-chloropropionyl chloride and aniline in two steps.
[storage]

Store at -20°C
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P280-P261
[WGK Germany ]

3
[HS Code ]

2933790090
Spectrum DetailBack Directory
[Spectrum Detail]

3-METHYLOXINDOLE 96(1504-06-9)1HNMR
1504-06-9 suppliers list
Company Name: CAREBIO PHARMA  Gold
Telephone: 18501057619 18501057619
Website: https://www.chemicalbook.com/supplier/25966678/
Company Name: Changsha YuTeng New Materials Co., Ltd.  Gold
Telephone: 13487087296; 13487087296
Website: https://csyuteng.cn/
Company Name: J & K SCIENTIFIC LTD.  
Telephone: 18210857532 18210857532
Website: https://www.jkchemical.com
Company Name: Alfa Aesar  
Telephone: 400-6106006
Website: http://chemicals.thermofisher.cn
Company Name: Energy Chemical  
Telephone: 400-0056266
Website: www.energy-chemical.com
Company Name: Shanghai Hanhong Scientific Co.,Ltd.  
Telephone: 021-54306202 13764082696
Website: https://www.hanhongsci.com
Company Name: Chemsky (shanghai) International Co.,Ltd  
Telephone: 021-50135380
Website: www.shchemsky.com
Company Name: China DongFan Chemical Co.,LTD  
Telephone: 86-0571-85151182
Website: www.chemicalbook.com/ShowSupplierProductsList14819/0_EN.htm
Company Name: Shandong Xiya Chemical Co., Ltd  
Telephone: 13355009207 13355009207
Website: http://www.xiyashiji.com
Company Name: Chengdu Ai Keda Chemical Technology Co., Ltd.  
Telephone: 4008-755-333 18080918076
Website: http://www.aikeshiji.com
Company Name: 9ding chemical ( Shanghai) Limited  
Telephone: 4009209199
Website: www.9dingchem.com
Company Name: Shanghai Aladdin Bio-Chem Technology Co.,LTD  
Telephone: 400-6206333 13167063860
Website: www.aladdin-e.com/
Company Name: HuBei ShengBaoLai Biological Technology Co., Ltd  
Telephone: 027-59105235 13007105135
Website: http://www.hubeisbl-bio.com
Company Name: Shanghai JONLN Reagent Co., Ltd.  
Telephone: 400-0066400 13621662912
Website: http://www.jonln.com
Company Name: Bide Pharmatech Ltd.  
Telephone: 400-164-7117 18317119277
Website: www.bidepharm.com
Company Name: Chemwill Asia Co.,Ltd.  
Telephone: 86-21-51086038
Website: www.chemwill.com
Company Name: Chengdu HuaXia Chemical Reagent Co. Ltd  
Telephone: 400-1166-196 13458535857
Website: http://www.hx-r.com
Company Name: Tianjin Anhao Biological Technology Co., Ltd.  
Telephone:
Website: www.glsyntech.com
Tags:1504-06-9 Related Product Information
108-99-6 3268-49-3 16630-52-7 505-10-2