ChemicalBook--->CAS DataBase List--->15475-27-1

15475-27-1

15475-27-1 Structure

15475-27-1 Structure
IdentificationBack Directory
[Name]

POTASSIUM DIPHENYLPHOSPHIDE
[CAS]

15475-27-1
[Synonyms]

KPPh2
Potassium diphenyL
POTASSIUM DIPHENYLPHOSPHIDE
Potassium diphenylphosphine
Potassium diphenylphosphanide
DIPHENYLPHOSPHINE POTASSIUM SALT
POTASSIUM DIPHENYLPHOSFIDE SOLUTION
potassium diphenylphosphide solution
POTASSIUM DIPHENYLPHOSPHIDE, 0.5M SOLUTI
Phosphine, diphenyl-,potassium salt (1:1)
POTASSIUM DIPHENYLPHOSPHIDE ISO 9001:2015 REACH
Potassium diphenylphosphide solution 0.5 in THF
POTASSIUM DIPHENYLPHOSPHIDE SOLUTION, ~0 .5 M IN THF
Potassium Diphenylphosphide (ca. 0.5mol/L in Tetrahydrofuran)
Potassium diphenylphosphide solution,Diphenylphosphine potassium salt
[Molecular Formula]

C12H12KP
[MDL Number]

MFCD00134530
[MOL File]

15475-27-1.mol
[Molecular Weight]

226.3
Chemical PropertiesBack Directory
[density ]

0.929 g/mL at 25 °C
[Fp ]

−4 °F
[form ]

liquid
[BRN ]

4164304
[InChI]

1S/C12H10P.K/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1
[InChIKey]

FCLYZQXPJKJTDR-UHFFFAOYSA-N
[SMILES]

[K]P(c1ccccc1)c2ccccc2
Safety DataBack Directory
[Symbol(GHS) ]


GHS02,GHS05,GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H225-H302-H314-H335-H351
[Precautionary statements ]

P210-P260-P280-P305+P351+P338-P370+P378-P403+P235
[Hazard Codes ]

F,C
[Risk Statements ]

11-19-22-34-40-37
[Safety Statements ]

16-26-33-36/37/39-45
[RIDADR ]

UN 2924 3/PG 2
[WGK Germany ]

1
[F ]

1-8-10-13
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 4 Oral
Carc. 2
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3
Hazard InformationBack Directory
[Uses]


  • Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta5: eta1-C5Me4CH2PPh2)Re(CO)2.: This study explores the synthesis and reactivity of a novel phosphino complex, utilizing Potassium diphenylphosphide as a key reagent. The research highlights the molecular structure and potential applications in organometallic chemistry (Godoy et al., 2009).

  • Improved and efficient synthesis of chiral N,P-ligands via cyclic sulfamidates for asymmetric addition of butyllithium to benzaldehyde.: This paper details an improved synthesis method for chiral N,P-ligands using Potassium diphenylphosphide. The research demonstrates the compound′s efficacy in asymmetric synthesis, offering potential advancements in drug discovery and development (Rönnholm et al., 2007).

  • Coordination chemistry of diselenophosphinate complexes: the X-ray single-crystal structures of [K(Se2PPh2)(THF)2]2 and [In(Se2PPh2)3].L (L = THF, PhMe).: This article investigates the coordination chemistry involving diselenophosphinate complexes, with Potassium diphenylphosphide playing a crucial role. The study provides detailed X-ray crystallographic data, offering insights for future research in chemical synthesis and materials science (Davies et al., 2004).


[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
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