ChemicalBook--->CAS DataBase List--->156783-95-8

156783-95-8

156783-95-8 Structure

156783-95-8 Structure
IdentificationBack Directory
[Name]

Carbonic acid, Methyl 2,2,2-trifluoroethyl ester
[CAS]

156783-95-8
[Synonyms]

Methyl trifluoroethyl carbonate
Methyl trifluoroethylene carbonate
Methyl2,2,2-trifluoroethylcarbonate
2,2,2-trifluoroethyl Methyl carbonate
Methyl 2,2,2-trifluoroethyl carbonate 97%
Carbonic acid, Methyl 2,2,2-trifluoroethyl ester
[EINECS(EC#)]

694-997-5
[Molecular Formula]

C4H5F3O3
[MDL Number]

MFCD28054295
[MOL File]

156783-95-8.mol
[Molecular Weight]

158.08
Questions And AnswerBack Directory
[Preparation]

Trifluoroethanol, methyl chloroformate, and an aqueous solution of potassium hydroxide are fed into the reaction zone of the reactor, where they react to produce Carbonic acid, Methyl 2,2,2-trifluoroethyl ester.

Chemical PropertiesBack Directory
[Boiling point ]

74.2±40.0 °C(Predicted)
[density ]

1.308g/ml
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

liquid
[color ]

Clear, almost colourless
[Major Application]

battery manufacturing
[InChI]

InChI=1S/C4H5F3O3/c1-9-3(8)10-2-4(5,6)7/h2H2,1H3
[InChIKey]

GBPVMEKUJUKTBA-UHFFFAOYSA-N
[SMILES]

C(OCC(F)(F)F)(=O)OC
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)
GHS02
[Signal word ]

Danger
[Hazard statements ]

H225
[Precautionary statements ]

P210-P233-P240-P241-P242-P243-P280-P303+P361+P353-P370+P378-P403+P235-P501
[RIDADR ]

UN3272
[WGK Germany ]

WGK 3
[HazardClass ]

3
[HS Code ]

2933399990
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Description]

Methyl (2,2,2-trifluoroethyl) carbonate (FEMC; Carbonic acid, Methyl 2,2,2-trifluoroethyl ester), ≥99%, battery grade is one kind of fluorinated linear carbonate. It comes with very low water content (≤ 300.0 ppm) and low impurity of HF (≤ 250.0 ppm) which is ideal for battery research.
[Chemical Properties]

Methyl trifluoroethyl carbonate is a fluorine substitute additive for electrolyte, which has the characteristics of high voltage resistance and easy film formation, and its stability is relatively good under high voltage.
[Application]

Battery-grade methyl (2,2,2-trifluoroethyl) carbonate (FEMC; Carbonic acid, Methyl 2,2,2-trifluoroethyl ester) is an effective additive for improving the performance and stability of lithium-ion batteries. Its outstanding thermal and electrochemical stability makes it a reliable option for high-temperature and high-voltage battery applications. FEMC has been shown to improve battery life, enhance energy density, and increase cycling stability. As an electrolyte additive in lithium-ion batteries (LIBs), FEMC plays a vital role in forming a stable solid electrolyte interphase (SEI) and effective passivation of the cathode surfaces, resulting in enhanced discharge capacity and cyclability. Even adding 5 wt % of FEMC was found to be very effective in forming a stable SEI layer and protecting the surface of the cathode. FEMC's high performance makes it an attractive choice for battery manufacturers looking to create safe and efficient battery products.
Spectrum DetailBack Directory
[Spectrum Detail]

Carbonic acid, Methyl 2,2,2-trifluoroethyl ester (156783-95-8)1HNMR
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