| Identification | Back Directory | [Name]
BENZYLMAGNESIUM BROMIDE | [CAS]
1589-82-8 | [Synonyms]
benzylbromomagnesium
Bromobenzylmagnesium
BENZYLMAGNESIUM BROMIDE
Bromo(phenylmethyl)magnesium
BenzylMagnesiuM BroMide
Magnesium,bromo(phenylmethyl)-
BenzylMagnesiuM BroMide, 1M in THF
magnesium methanidylbenzene bromide
(ca. 12% in Tetrahydrofuran, ca. 0.6Mol/L)
Benzylmagnesium bromide 1M solution in THF
Benzylmagnesium bromide 1M solution in DEE
benzyl-magnesium bromide 1M tetrahydrofuran
Benzylmagnesium bromide 0.5M solution in THF
BenzylMagnesiuM BroMide 1M in Tetrahydrofuran
Benzylmagnesium bromide 0.5M solution in 2Me-THF
BenzylMagnesiuM broMide, 0.9M solution in THF, SpcSeal
Benzylmagnesium Bromide (19% in Tetrahydrofuran, ca. 1mol/L)
Benzylmagnesium Bromide (ca. 12% in Tetrahydrofuran, ca. 0.6mol/L)
BenzylMagnesiuM BroMide (ca. 18% in Tetrahydrofuran, ca. 0.9Mol/L) | [EINECS(EC#)]
216-459-7 | [Molecular Formula]
C7H7BrMg | [MDL Number]
MFCD00209956 | [MOL File]
1589-82-8.mol | [Molecular Weight]
195.34 |
| Hazard Information | Back Directory | [Uses]
Benzylmagnesium Bromide is mainly used for the formation of diastereomeric o-toluylmethanol via a format reaction. Moreover, benzylmagnesium bromide only generates o-tolylmethanol when used in excess or at higher temperatures[1]. | [storage]
Store under inert gas | [References]
[1] MARO\VS BELLA. Reaction of selected carbohydrate aldehydes with benzylmagnesium halides: benzyl versus o-tolyl rearrangement.[J]. Beilstein Journal of Organic Chemistry, 2014: 1942-1950. DOI:10.3762/bjoc.10.202. |
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