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16112-10-0

16112-10-0 Structure

16112-10-0 Structure
IdentificationBack Directory
[Name]

1-ACETYL-1-CYCLOPENTENE
[CAS]

16112-10-0
[Synonyms]

1-acetylcyclopentene
1-ACETYL-1-CYCLOPENTENE
1-Acetylcyclopent-1-ene
1-cyclopentenylethanone
1-Cyclopent-1-enyl-ethanone
1-(1-Cyclopentenyl)ethanone
1-Acetyl-1-cyclopentene 97%
1-(cyclopenten-1-yl)ethanone
Methyl (1-cyclopentenyl) ketone
1-(cyclopent-1-en-1-yl)ethanone
Ethanone, 1-(1-cyclopenten-1-yl)-
1-(Cyclopent-1-en-1-yl)ethan-1-one
Ethanone, 1-(1-cyclopenten-1-yl)- (9CI)
1-ACETYL-1-CYCLOPENTENE ISO 9001:2015 REACH
[Molecular Formula]

C7H10O
[MDL Number]

MFCD00799464
[MOL File]

16112-10-0.mol
[Molecular Weight]

110.15
Chemical PropertiesBack Directory
[Boiling point ]

70 °C/20 mmHg (lit.)
[density ]

0.955 g/mL at 25 °C (lit.)
[refractive index ]

n20/D 1.483(lit.)
[Fp ]

59 °C
Safety DataBack Directory
[RIDADR ]

UN 1224 3/PG 3
[WGK Germany ]

3
[HS Code ]

2914290090
Hazard InformationBack Directory
[Uses]

1-Acetyl-1-cyclopentene may be used in the preparation of the following allenylcycloalkanes:
  • 1-vinylidenyl-2-[4-(trimethylsilyl)-3-butynyl]-cyclopentane
  • 1-vinylidenyl-2-(3-butynyl)-cyclopentane
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 44, p. 450, 1979 DOI: 10.1021/jo01317a033
Tetrahedron Letters, 15, p. 1623, 1974
[General Description]

1-Acetyl-1-cyclopentene is a cyclic alkene. Its lithium enolate undergoes Brook rearrangement-mediated [3+4] annulation with 3-alkyl-3-haloacryloylsilanes to afford tricyclo[5.3.0.01,4]decenone derivatives. Asymmetric oxidative Heck reaction of 1-acetyl-1-cyclopentene in the presence of a Pd-ligand has been reported.
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