| Identification | Back Directory | [Name]
BIS(DIETHYLAMINO)PHENYLPHOSPHINE 97 | [CAS]
1636-14-2 | [Synonyms]
NSC 244337
Phenylphosphonous tetraethyldiamide
Bis(diethylamino)phenylphosphine 97%
BIS(DIETHYLAMINO)PHENYLPHOSPHINE 97
N,N,N′N′-Tetraethylphenylphosphonous diamide
Phosphonous diamide, N,N,N',N'-tetraethyl-P-phenyl- | [Molecular Formula]
C14H25N2P | [MDL Number]
MFCD00137954 | [MOL File]
1636-14-2.mol | [Molecular Weight]
252.34 |
| Chemical Properties | Back Directory | [Boiling point ]
80 °C0.005 mm Hg(lit.) | [density ]
0.971 g/mL at 25 °C(lit.) | [Fp ]
223 °F | [form ]
liquid | [pka]
6.94±0.70(Predicted) | [InChI]
1S/C14H25N2P/c1-5-15(6-2)17(16(7-3)8-4)14-12-10-9-11-13-14/h9-13H,5-8H2,1-4H3 | [InChIKey]
HTIVDCMRYKVNJC-UHFFFAOYSA-N | [SMILES]
CCN(CC)P(N(CC)CC)c1ccccc1 |
| Hazard Information | Back Directory | [Uses]
- Electron-withdrawing cocatalyst in rhodium catalyzed hydroformylation reactions
- Ligand precatalyst for Heck coupling reactions
Reactant for:
- Preparation of palladium chiral P-N ligand complexes for regio- and stereo-selective dimerization reactions
- Preparation of palladium tautomeric ferrocenylphosphinites as catalysts for Suzuki-Miyaura coupling
- Trimethylsilyl halide-promoted Michaelis-Arbuzov rearrangement of phosphinites and phosphites
| [Uses]
Electron-withdrawing cocatalyst in rhodium catalyzed hydroformylation reactions. Ligand precatalyst for Heck coupling reactions. Reactant for: Preparation of palladium chiral P-N ligand complexes for regio- and stereo-selective dimerization reactions. Preparation of palladium tautomeric ferrocenylphosphinites as catalysts for Suzuki-Miyaura coupling. Trimethylsilyl halide-promoted Michaelis-Arbuzov rearrangement of phosphinites and phosphites. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
|
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Henan Alpha Chemical Co., Ltd.
|
| Telephone: |
0371-55055611 18137792234 |
| Website: |
https://www.chemicalbook.com/ShowSupplierProductsList31206/0.htm |
| Company Name: |
Shaanxi Dideu Medichem Co. Ltd
|
| Telephone: |
+86-29-81139210 17389186172 |
| Website: |
https://www.chemicalbook.com/manufacturer/shaanxi-dideu-medichem-219/ |
|