ChemicalBook--->CAS DataBase List--->1636-14-2

1636-14-2

1636-14-2 Structure

1636-14-2 Structure
IdentificationBack Directory
[Name]

BIS(DIETHYLAMINO)PHENYLPHOSPHINE 97
[CAS]

1636-14-2
[Synonyms]

NSC 244337
Phenylphosphonous tetraethyldiamide
Bis(diethylamino)phenylphosphine 97%
BIS(DIETHYLAMINO)PHENYLPHOSPHINE 97
N,N,N′N′-Tetraethylphenylphosphonous diamide
Phosphonous diamide, N,N,N',N'-tetraethyl-P-phenyl-
[Molecular Formula]

C14H25N2P
[MDL Number]

MFCD00137954
[MOL File]

1636-14-2.mol
[Molecular Weight]

252.34
Chemical PropertiesBack Directory
[Boiling point ]

80 °C0.005 mm Hg(lit.)
[density ]

0.971 g/mL at 25 °C(lit.)
[Fp ]

223 °F
[form ]

liquid
[pka]

6.94±0.70(Predicted)
Safety DataBack Directory
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

  • Electron-withdrawing cocatalyst in rhodium catalyzed hydroformylation reactions
  • Ligand precatalyst for Heck coupling reactions

Reactant for:
  • Preparation of palladium chiral P-N ligand complexes for regio- and stereo-selective dimerization reactions
  • Preparation of palladium tautomeric ferrocenylphosphinites as catalysts for Suzuki-Miyaura coupling
  • Trimethylsilyl halide-promoted Michaelis-Arbuzov rearrangement of phosphinites and phosphites
[Uses]

Electron-withdrawing cocatalyst in rhodium catalyzed hydroformylation reactions. Ligand precatalyst for Heck coupling reactions. Reactant for: Preparation of palladium chiral P-N ligand complexes for regio- and stereo-selective dimerization reactions. Preparation of palladium tautomeric ferrocenylphosphinites as catalysts for Suzuki-Miyaura coupling. Trimethylsilyl halide-promoted Michaelis-Arbuzov rearrangement of phosphinites and phosphites.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
Spectrum DetailBack Directory
[Spectrum Detail]

BIS(DIETHYLAMINO)PHENYLPHOSPHINE 97(1636-14-2)IR
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