ChemicalBook--->CAS DataBase List--->1644049-46-6

1644049-46-6

1644049-46-6 Structure

1644049-46-6 Structure
IdentificationBack Directory
[Name]

Spiro[acridine-9(10H),9'-[9H]thioxanthene]
[CAS]

1644049-46-6
[Synonyms]

Spiro[acridine-9(10H),9'-[9H]thioxanthene]
[Molecular Formula]

C25H17NS
[MOL File]

1644049-46-6.mol
[Molecular Weight]

363.47
Chemical PropertiesBack Directory
[Boiling point ]

521.3±50.0 °C(Predicted)
[density ]

1.35±0.1 g/cm3(Predicted)
[pka]

0.45±0.20(Predicted)
[InChI]

InChI=1S/C25H17NS/c1-5-13-21-17(9-1)25(18-10-2-6-14-22(18)26-21)19-11-3-7-15-23(19)27-24-16-8-4-12-20(24)25/h1-16,26H
[InChIKey]

JAUADISATOQBGC-UHFFFAOYSA-N
[SMILES]

C1=C2C(NC3=C(C42C2=C(C=CC=C2)SC2=C4C=CC=C2)C=CC=C3)=CC=C1
Hazard InformationBack Directory
[Uses]

Spiro[acridine-9(10H),9'-[9H]thioxanthene], also known as 10H-spiro(acridine-9,9′- thioxanthene) (TXDMAc), is commonly used in TADF emitter as a donor. The compound BPy3-TXDMAc based on Spiro[acridine-9(10H),9'-[9H]thioxanthene] can be used for OLEDs preparation. In particular, OLEDs employing BPy3-TXDMAc dopant realized maximum external quantum efficiencies (EQEs) up to 25.6%. Moreover, the nondoped device based on BPy3-TXDMAc exhibited a maximum EQE of 18.7%, accompanied by an extremely small efficiency loss of only 4.1% at the luminance of 1000 cd m-2[1].
[References]

[1] Wang L, et al. Achieving Enhanced Thermally Activated Delayed Fluorescence Rates and Shortened Exciton Lifetimes by Constructing Intramolecular Hydrogen Bonding Channels. ACS Applied Materials & Interfaces, 2019; 49: 45999–46007.
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