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16644-98-7

16644-98-7 Structure

16644-98-7 Structure
IdentificationBack Directory
[Name]

(1E)-1-Iodo-1-hexene
[CAS]

16644-98-7
[Synonyms]

1-iodohex-1-ene
trans-1-Iodohexene
1(E)-Iodo-hex-1-ene
(E)-1-Iodo-1-hexene
(1E)-1-Iodo-1-hexene
(E)-1-Hexenyl iodide
trans-1-Iodo-1-hexene
1-Hexene, 1-iodo-, (1E)-
(1E)-1-Iodo-1-hexene ISO 9001:2015 REACH
[Molecular Formula]

C6H11I
[MDL Number]

MFCD00798209
[MOL File]

16644-98-7.mol
[Molecular Weight]

210.06
Chemical PropertiesBack Directory
[Boiling point ]

151.64°C (estimate)
[density ]

1.4517 (rough estimate)
[refractive index ]

n20/D 1.509
[BRN ]

1840329
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302
[Precautionary statements ]

P264-P270-P301+P312-P330-P501
[Hazard Codes ]

Xn,N
[Risk Statements ]

22-51/53
[Safety Statements ]

61
[RIDADR ]

UN 3082 9 / PGIII
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

Palladium-catalyzed carboalkoxylation gives appreciable stereospecific vinylic halides, including trans-1-Iodohexene. Also, trans-1-Iodohexene cross coupled with (E)??- or (Z)??-??vinylstannanes gives good yields of stereoisomerically pure unsymmetrical dienes with the same double bond geometry
[Synthesis Reference(s)]

Tetrahedron Letters, 15, p. 543, 1974 DOI: 10.1016/S0040-4039(01)82266-8
The Journal of Organic Chemistry, 54, p. 6064, 1989 DOI: 10.1021/jo00287a017
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