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17172-16-6

17172-16-6 Structure

17172-16-6 Structure
IdentificationBack Directory
[Name]

Dihydrovindolinine
[CAS]

17172-16-6
[Synonyms]

Pseudoervinine
Pseudokopsinin
Pseudokopsinine
Dihydrovindolinine
(-)-Pseudocopsinine
14,15-Dihydrovindolinine
2,20-Cycloaspidospermidine-3-carboxylic acid, methyl ester, (3β,5α,12R,19α,20R)-
[Molecular Formula]

C21H26N2O2
[MOL File]

17172-16-6.mol
[Molecular Weight]

338.44
Chemical PropertiesBack Directory
[Occurrence]

The absolute configuration of this alkaloid has now been established from spectroscopic data.
[Melting point ]

136-188 °C(Solvent: Benzene)
[Boiling point ]

482.364±45.00 °C(Press: 760.00 Torr)(predicted)
[density ]

1.296±0.10 g/cm3(Temp: 25 °C; Press: 760 Torr)(predicted)
[pka]

9.045±0.60(predicted)
Hazard InformationBack Directory
[Description]

The aerial parts of Vinca erecta yield this imidazolidinocarbazole alkaloid which has been characterized as the epi-base formed on heating with NaOMe in NaOH and giving a crystalline hydrochloride, m.p. 2S7-9°C (dec.); [α]D + 92.1° (MeOH). Treatment of the alkaloid with lead acetate gives the dehydro derivative, m.p. 188-1910C; [α]D + 62° (MeOH).
[References]

Abdurakhimova, Yuldashev, Yunusov., Dok!. Akad. Nauk. SSSR, 173,87 ( 1967)
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