ChemicalBook--->CAS DataBase List--->173035-11-5

173035-11-5

173035-11-5 Structure

173035-11-5 Structure
IdentificationBack Directory
[Name]

1,3-Dimesitylimidazolidin-2-ylidene
[CAS]

173035-11-5
[Synonyms]

SIMes
IMesH2
1,3-Dimesitylimidazolidin-2-ylidene
1,3-Bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene
1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene
1,3-Bis(2,4,6-trimethyphenyl)4,5- dihydroimidazol-2-ylidene
1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene
1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene,98%
1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydro-2H-imidazol-1-ium-2-ide
1,3-Bis(2,4,6-trimethylphenyl)-4,5- dihydroimidazol-2-ylidene, min. 98%
[Molecular Formula]

C21H26N2
[MDL Number]

MFCD11973794
[MOL File]

173035-11-5.mol
[Molecular Weight]

306.45
Chemical PropertiesBack Directory
[Melting point ]

85-100°C
[storage temp. ]

?20°C
[form ]

Powder
[color ]

pale yellow
[Sensitive ]

air sensitive, moisture sensitive
[InChI]

1S/C21H26N2/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6/h9-12H,7-8H2,1-6H3
[InChIKey]

LSMWOQFDLBIYPM-UHFFFAOYSA-N
[SMILES]

Cc1cc(C)c(N2[C]N(CC2)c3c(C)cc(C)cc3C)c(C)c1
Safety DataBack Directory
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reactions]

  1. Ligand for copper-catalyzed regioselective formation of tri- and tetrasubstituted vinylboronates in air.
  2. Ligand for highly active ruthenium catalyst for hydrogenation of olefins.
  3. Electrophilic phosphonium cations component for ketone catalytic hydrodeoxygenation/hydrosilylation.
  4. Used in selective activation of fluoroalkenes to produce N-heterocyclic fluoroalkenes and polyfluoroalkenyl imidazolium salts.
Reactions of 173035-11-5
Hazard InformationBack Directory
[reaction suitability]

reagent type: catalyst
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