| Identification | Back Directory | [Name]
1,3-Dimesitylimidazolidin-2-ylidene | [CAS]
173035-11-5 | [Synonyms]
SIMes
IMesH2
1,3-Dimesitylimidazolidin-2-ylidene
1,3-Bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene
1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene
1,3-Bis(2,4,6-trimethyphenyl)4,5- dihydroimidazol-2-ylidene
1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene
1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene,98%
1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydro-2H-imidazol-1-ium-2-ide
1,3-Bis(2,4,6-trimethylphenyl)-4,5- dihydroimidazol-2-ylidene, min. 98% | [Molecular Formula]
C21H26N2 | [MDL Number]
MFCD11973794
| [MOL File]
173035-11-5.mol | [Molecular Weight]
306.45 |
| Chemical Properties | Back Directory | [Melting point ]
85-100°C | [storage temp. ]
?20°C | [form ]
Powder | [color ]
pale yellow | [Sensitive ]
air sensitive, moisture sensitive | [InChI]
1S/C21H26N2/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6/h9-12H,7-8H2,1-6H3 | [InChIKey]
LSMWOQFDLBIYPM-UHFFFAOYSA-N | [SMILES]
Cc1cc(C)c(N2[C]N(CC2)c3c(C)cc(C)cc3C)c(C)c1 |
| Questions And Answer | Back Directory | [Reactions]
- Ligand for copper-catalyzed regioselective formation of tri- and tetrasubstituted vinylboronates in air.
- Ligand for highly active ruthenium catalyst for hydrogenation of olefins.
- Electrophilic phosphonium cations component for ketone catalytic hydrodeoxygenation/hydrosilylation.
- Used in selective activation of fluoroalkenes to produce N-heterocyclic fluoroalkenes and polyfluoroalkenyl imidazolium salts.
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