| Identification | Back Directory | [Name]
ETHYLENE GLYCOL BIS(4-TRIMELLITATE ANHYDRIDE) | [CAS]
1732-96-3 | [Synonyms]
TMEG
JACS-1732-96-3
Ethylene glycol bis(anhydrotrimellitate)
Ethylene glycol bis(trimellitic anhydride)
ETHYLENE GLYCOL BIS(4-TRIMELLITATE ANHYDRIDE)
ETHYLENE GLYCOL BIS(4-TRIMELLITATE ANHYDRIDE) (TMEG)
Bis(1,3-dioxoisobenzofuran-5-carboxylic acid)ethylene ester
5,5'-[Ethylenebis(oxycarbonyl)]bis(isobenzofuran-1,3-dione)
1,2,4-Benzenetricarboxylic acid 1,2-anhydride ethylene ester
ethylene bis[1,3-dihydro-1,3-dioxoisobenzofuran-5-carboxylate]
1,2,4-Benzenetricarboxylic acid cyclic 1,2-anhydride ethylene ester
4,4'-[Ethylenebis(oxycarbonyl)]diphthalic acid 1,2:1',2'-dianhydride
Ethane-1,2-diyl bis(1,3-dioxo-1,3-dihydroisobenzofuran-5-carboxylate)
Bis(1,3-dihydro-1,3-dioxoisobenzofuran-5-carboxylic acid)ethylene ester
5-Isobenzofurancarboxylic acid, 1,3-dihydro-1,3-dioxo-, 1,2-ethanediyl ester
Bis(1,3-dihydro-1,3-dioxo-5-isobenzofurancarboxylic acid)1,2-ethanediyl ester
Ethylene glycol diester with 1,2,4-benzenetricarboxylic acid cyclic 1,2-anhydride
2-(1,3-Dioxo-2-benzofuran-5-carbonyl)oxyethyl 1,3-dioxo-2-benzofuran-5-carboxylate
5-Isobenzofurancarboxylic acid, 1,3-dihydro-1,3-dioxo-, 5,5'-(1,2-ethanediyl) ester | [EINECS(EC#)]
217-062-1 | [Molecular Formula]
C20H10O10 | [MDL Number]
MFCD00082947 | [MOL File]
1732-96-3.mol | [Molecular Weight]
410.29 |
| Chemical Properties | Back Directory | [Melting point ]
167-169℃ | [Boiling point ]
681.8±50.0 °C(Predicted) | [density ]
1.625 | [vapor pressure ]
0.002Pa at 25℃ | [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
Solid:particulate/powder | [Appearance]
White to light yellow Solid | [InChI]
InChI=1S/C20H10O10/c21-15(9-1-3-11-13(7-9)19(25)29-17(11)23)27-5-6-28-16(22)10-2-4-12-14(8-10)20(26)30-18(12)24/h1-4,7-8H,5-6H2 | [InChIKey]
XQBLBHYWXZNCJZ-UHFFFAOYSA-N | [SMILES]
C(OC(C1C=CC2C(=O)OC(=O)C=2C=1)=O)COC(C1C=CC2C(=O)OC(=O)C=2C=1)=O | [LogP]
3.33 at 30℃ and pH1.5 |
| Hazard Information | Back Directory | [Chemical Properties]
White to off-white powder | [Synthesis]
Trimellitic anhydride (1.0 mol, 192 g) was mixed with ethylene glycol (0.55 mol, 34 g) in a reactor and nitrogen was vented to remove air. The reaction mixture was heated to 230-240°C under continuous nitrogen protection, during which water was generated and distilled. When the amount of water distilled approached the theoretical value (18 g), the system pressure was reduced to 10-15 mmHg while the temperature was raised to 260°C and the reaction was maintained at this condition for 2 hours. Upon completion of the reaction, the reaction mixture was cooled and recrystallized from 900-1200 g of acetone to afford the intermediate ethylene glycol trimellitate as a white powder (176 g, 86% yield). Subsequently, the intermediate was dissolved in 5% aqueous sodium hydroxide solution and hydrolyzed by adjusting the pH to 1-3 with dilute hydrochloric acid, and dried after completion of the reaction to obtain the final product ethylene glycol trimellitate as white powder (211.8 g, 95% yield). | [References]
[1] Patent: CN105968050, 2016, A. Location in patent: Paragraph 0060; 0061 |
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