173416-05-2

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173416-05-2 Structure

Identification	Back Directory
[Name] HYDRIDO(DIMETHYLPHOSPHINOUS ACID-KP)[HYDROGEN BIS(DIMETHYLPHOSPHINITO-KP)]PLATINUM (II)
[CAS] 173416-05-2
[Synonyms] HYDRIDO(DIMETHYLPHOSPHINOUS ACID-KP)[HYDROGEN BIS(DIMETHYLPHOSPHINITO-KP)]PLATINUM (II)
[Molecular Formula] C6H19O3P3Pt
[MDL Number] MFCD08459361
[MOL File] 173416-05-2.mol
[Molecular Weight] 427.21

Chemical Properties	Back Directory
[form ] Powder
[color ] white to off-white

Safety Data	Back Directory
[Symbol(GHS) ] GHS07
[Signal word ] Warning
[Hazard statements ] H335-H315-H319
[Precautionary statements ] P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362

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[Reaction]

Widely used in complex multi-step organic syntheses. This mild hydration catalyst converts hindered and acid/base sensitive nitriles to amides. The amide is released from the metal coordination sphere preventing further hydrolysis to acid. Typically, turnover frequency (TOF) ranges from 16 to 380 h-1 depending on steric factors. For optimal results avoid the presence of coordinating anions especially cyanide and halide. Reactions of 173416-05-2

Hazard Information	Back Directory
[Uses] Parkins’ Catalyst promotes the efficient nitriles hydration to amides by the phosphine oxide addition to nitrile.

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