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175845-21-3

175845-21-3 Structure

175845-21-3 Structure
IdentificationBack Directory
[Name]

2,8,9-TRI-I-PROPYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
[CAS]

175845-21-3
[Synonyms]

2,8,9-TRIISOPROPYL-2,5,8,9-TETRAAZA-1-P&
2,8,9-TRIISOPROPYL-2,5,8,9-TETRAZA-1-PH&
2,8,9-TRIISOPROPYL-2,5,8,9-TETRAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
2,8,9-TRI-I-PROPYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
2,8,9-TRIISOPROPYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
4,6,11-tri(propan-2-yl)-1,4,6,11-tetraza-5-phosphabicyclo[3.3.3]undecane
2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE,2,8,9-TRIS(1-METHYLETHYL)
2,8,9-Tris(1-methylethyl)-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane
2,8,9-triisopropyl-2,5,8,9-tetraza-1-phosphabicyclo[3.3.3]undecane solution
2,8,9-Triisopropyl-2,5,8,9-tetraaza-1-phosphabicyclo[3,3,3]undecane solution
2,8,9-Triisopropyl-2,5,8,9-tetraza-1-phosphabicyclo[3.3.3]undecane solution 1 M in toluene
[Molecular Formula]

C15H33N4P
[MDL Number]

MFCD03701530
[MOL File]

175845-21-3.mol
[Molecular Weight]

300.42
Chemical PropertiesBack Directory
[Boiling point ]

351.4±41.0 °C(Predicted)
[density ]

0.922 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.4830(lit.)
[Fp ]

46 °F
[form ]

liquid
[pka]

9.37±0.20(Predicted)
[color ]

yellow
[Specific Gravity]

0.922
[Sensitive ]

moisture sensitive
[InChI]

1S/C15H33N4P/c1-13(2)17-10-7-16-8-11-18(14(3)4)20(17)19(12-9-16)15(5)6/h13-15H,7-12H2,1-6H3
[InChIKey]

DFRWCJYSXGNOFD-UHFFFAOYSA-N
[SMILES]

CC(C)N1CCN2CCN(C(C)C)P1N(CC2)C(C)C
Safety DataBack Directory
[Hazard Codes ]

F,Xn
[Risk Statements ]

11-38-48/20-63-65-67
[Safety Statements ]

36/37-62-24/25-16
[RIDADR ]

UN 1294 3/PG 2
[WGK Germany ]

3
[Storage Class]

10 - Combustible liquids
Questions And AnswerBack Directory
[Reaction]

Exceedingly strong, non-ionic Brønsted and Lewis base useful in a variety of organic transformations.
Hazard InformationBack Directory
[Uses]

Base used in an attempt to produce higherly reactive no-carrier-added fluoride for labeling of radiopharmaceuticals and used in the synthesis of monomeric alumatranes

Deprotonation agent used to study the nucleophilic reactivities of benzenesulfonyl-substituted carbanions

Catalyst involved in:
  • Synthesis of polymer-supported proazaphosphatranes for catalysis of amidation and transesterification reactions
  • Wadsworth-Emmons reactions
  • Mukaiyama aldol reactions
  • Synthesis of aryl alcohols via addition reactions
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