| Identification | Back Directory | [Name]
Bis(triphenylphosphine)(maleic anhydride) palladium(0) | [CAS]
17830-50-1 | [Synonyms]
Bis(triphenylphosphine)(maleic anhydride) palladium(0) | [Molecular Formula]
C40H32O3P2Pd | [MDL Number]
MFCD01318339 | [MOL File]
17830-50-1.mol | [Molecular Weight]
729.06 |
| Hazard Information | Back Directory | [Uses]
Bis(triphenylphosphine)(maleic anhydride) palladium(0) can be used as a zero-valent palladium complex to catalyze the dimerization of 1,3-dienes and 1,2-dienes. | [Preparation]
Reaction of Tetrakis(triphenylphosphine)palladium(0) with Maleic Anhydride at rt in benzene, benzene/THF, or THF3 yields the title complex as a stable monomeric species, which is purified by crystallization from methanol/hexane. Bis(triphenylphosphine)(maleic anhydride) palladium(0) has also been synthesized from the putative bis(triphenylphosphine)palladium. |
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