| Identification | Back Directory | [Name]
(PHENYLTHIOMETHYL)TRIMETHYLSILANE | [CAS]
17873-08-4 | [Synonyms]
(PHENYLTHIOMETHYL)TRIMETHYLSILANE
PHENYLTHIO(TRIMETHYLSILYL)METHANE
TRIMETHYL(PHENYLTHIOMETHYL)SILANE
PHENYL TRIMETHYLSILYLMETHYL SULFIDE
Silane, trimethyl(phenylthio)methyl-
[[(Trimethylsilyl)methyl]thio]benzene
[(Trimethylsilyl)methyl]phenyl sulfide
Phenylthio(trimethylsilyl)methane
Phenyl Trimethylsilylmethyl Sulfide
Trimethyl(phenylthiomethyl)silane
(Phenylthiomethyl)trimethylsilane, (Trimethylsilyl)methyl phenyl sulfide, Phenyl (trimethylsilyl)methyl sulfide | [Molecular Formula]
C10H16SSi | [MDL Number]
MFCD00009838 | [MOL File]
17873-08-4.mol | [Molecular Weight]
196.38 |
| Chemical Properties | Back Directory | [Boiling point ]
158-159 °C52 mm Hg(lit.)
| [density ]
0.967 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.539(lit.)
| [Fp ]
103 °F
| [solubility ]
sol most common organic solvents. | [form ]
clear liquid | [color ]
Colorless to Almost colorless | [Specific Gravity]
0.97 | [Hydrolytic Sensitivity]
4: no reaction with water under neutral conditions | [BRN ]
1932375 | [NIST Chemistry Reference]
Silane, trimethyl[(phenylthio)methyl]-(17873-08-4) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
20-38 | [Safety Statements ]
23-28 | [RIDADR ]
UN 1993 3/PG 3
| [WGK Germany ]
3
| [HS Code ]
2931.90.6000 | [HazardClass ]
3.2 | [PackingGroup ]
III |
| Hazard Information | Back Directory | [Physical properties]
bp 158–159 °C/52 mmHg; d20 0.967 g cm?3; n20
D
1.5390. | [Uses]
lithio derivative is a one-carbon homologating agent leading to
aldehydes via sila-Pummerer rearrangement, vinyl sulfides via
Peterson alkenation, and vinylsilanes from silyl epoxides. | [Preparation]
(Phenylthiomethyl)trimethylsilane is abtained by reaction of Phenylthiomethyllithium with Chlorotrimethylsilane.[1] | [storage]
(Phenylthiomethyl)trimethylsilane is irriting; foul smelling; use in a fume hood. | [Purification Methods]
If the sample is suspect, then add H2O, wash it with 10% aqueous NaOH, H2O again, dry (anhydrous CaCl2) and fractionally distil it through a 2ft column packed with glass helices. [Cooper J Am Chem Soc 76 3713 1954.] | [References]
1. (a) Gilman, H.; Webb, F. J. JACS 1940, 62, 987. (b) Cooper, G. D. JACS 1954, 76, 3713. (c) Carey, F. A.; Court, A.
S. JOC 1972, 37, 939. |
|
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
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