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18077-77-5

18077-77-5 Structure

18077-77-5 Structure
IdentificationBack Directory
[Name]

tetraammonium uranyl tricarbonate, of uranium depleted in uranium-235
[CAS]

18077-77-5
[Synonyms]

Ammonium Uranium Carbonate
tetraammonium uranyl tricarbonate, of uranium depleted in uranium-235
[EINECS(EC#)]

241-988-5
[Molecular Formula]

C3O11U.4H4N
[Molecular Weight]

522.26
Chemical PropertiesBack Directory
[density ]

2.26 g/cm3(Temp: 57.00 °C)
[solubility ]

Sparingly soluble in water; insoluble in alcohol and ether
[form ]

Well-formed, transparent yellow crystals, monoclinic prismatic
Hazard InformationBack Directory
[Uses]

In uranium yellow glazes.
[Production Methods]

The (NH4)2U2O7 is precipitated from an aqueous solution of 10 g of UO2(NO3)2 ? 6 H2O by the addition of a cone. ammonia. The fine yellow powder is suction-filtered, washed with water, and stirred with an excess of cone. (NH4)2CO3 solution for about 10 minutes (the flask is on a 70°C water bath). The clear supernatant liquid is decanted and allowed to stand overnight. Yellow crystals precipitate; these are filtered with suction and dried in air. The residue of undissolved (NH4)2U2O7 is treated several times with the mother liquor at 70°C, as described above until crystals no longer form on cooling.
tetraammonium uranyl tricarbonate, of uranium depleted in uranium-235
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