| Identification | Back Directory | [Name]
Crotyltrimethylsilane | [CAS]
18292-28-9 | [Synonyms]
Crotyltrimethylsilane
Silane, 2-buten-1-yltrimethyl- | [Molecular Formula]
C7H16Si | [MDL Number]
MFCD09867901 | [MOL File]
18292-28-9.mol | [Molecular Weight]
128.29 |
| Hazard Information | Back Directory | [Precautions]
crotyltrimethylsilane is inflammable.
| [Preparation]
Crotyltrimethylsilane can be prepared separately from the exo- and endo-crotylpotassium compounds and Chlorotrimethylsilane, by nickel(II)-catalyzed coupling of (E)- or (Z)-1-bromopropene with (Chloromethyl)trimethylsilane, and by reaction of methylmagnesium iodide on 1,3-bis(trimethylsilyl)propene oxide followed by acid- or base-catalyzed (Peterson) desilylative elimination.
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