| Identification | Back Directory | [Name]
N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE | [CAS]
18303-04-3 | [Synonyms]
TsNBoc
LABOTEST-BB LT00453242
N-Boc-toluenesulfonamide
tert-Butyl tosylcarbamate
N-BOC-P-TOLUENESULFONAMIDE
tert-Butyl N-tosylcarbamate
(tert-Butoxycarbonyl)tosylamine
tert-Butyl N-(p-tosyl)carbamate
N-Boc-4-methylbenzenesulfonamide
Tosylcarbamic acid tert-butyl ester
N-Tosylcarbamic acid tert-butyl ester
N-(tert-Butoxycarbonyl-p-tolunesulfonamide
N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE
ert-butylN-(4-methylphenyl)sulfonylcarbamate
N-Boc-p-toluenesulfonamide, 99%, for synthesis
tert-butyl N-(4-methylphenyl)sulfonylcarbamate
N-(tert-Butoxycarbonyl)-p-toluenesulfonamide >
N-(p-Tolylsulfonyl)carbamic acid tert-butyl ester
N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE ISO 9001：2015 REACH
N-(tert-Butoxycarbonyl)-p-toluenesulfonamide
Carbamic acid,N-[(4-methylphenyl)sulfonyl]-, 1,1-dimethylethyl ester | [Molecular Formula]
C12H17NO4S | [MDL Number]
MFCD00134267 | [MOL File]
18303-04-3.mol | [Molecular Weight]
271.33 |
| Chemical Properties | Back Directory | [Melting point ]
121-123 °C(lit.)
| [density ]
1.201±0.06 g/cm3(Predicted) | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
chloroform: soluble25mg/mL, clear, colorless | [form ]
powder to crystal | [pka]
4.84±0.10(Predicted) | [color ]
White to Almost white | [InChI]
InChI=1S/C12H17NO4S/c1-9-5-7-10(8-6-9)18(15,16)13-11(14)17-12(2,3)4/h5-8H,1-4H3,(H,13,14) | [InChIKey]
DUTLOVSBVBGNDM-UHFFFAOYSA-N | [SMILES]
C(OC(C)(C)C)(=O)NS(C1=CC=C(C)C=C1)(=O)=O | [CAS DataBase Reference]
18303-04-3 |
| Hazard Information | Back Directory | [Description]
N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE is an useful component in Mitsunobu reactions for the direct preparation of protected amines from alcohols. | [Uses]
N-(tert-Butoxycarbonyl)-p-toluenesulfonamide may be used in the preparation of enyne amide, precursor for Pauson-Khand reaction. | [Synthesis Reference(s)]
Tetrahedron Letters, 35, p. 379, 1994 DOI: 10.1016/0040-4039(94)85058-5 | [General Description]
N-(tert-Butoxycarbonyl)-p-toluenesulfonamide is a N-substituted sulphonamide and its reaction with N-trityl L-serine esters under Mitsunobu reaction conditions is reported. It can be directly coupled with primary, secondary and allylic alcohols under Mitsunobu conditions to afford various sulfonyl-protected amines. | [storage]
N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE can be stored for extended periods of time in an amber bottle at rt. |
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J & K SCIENTIFIC LTD.
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Energy Chemical
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jiliang chemicals
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Maya High Purity Chemicals
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Sigma-Aldrich
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https://www.sigmaaldrich.cn |
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