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18388-03-9

18388-03-9 Structure

18388-03-9 Structure
IdentificationBack Directory
[Name]

2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE
[CAS]

18388-03-9
[Synonyms]

2-(CHLOROMETHYL)ALLYL-TRIMETHYLSILANE
2-(TRIMETHYLSILYLMETHYL)ALLYL CHLORIDE
2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE
2-Methylene-3-chloropropyltrimethylsilane
2-(Trimethylsilylmethyl)-3-chloro-1-propene
2-(chloromethyl)prop-2-enyl-trimethylsilane
[2-(Chloromethyl)-2-propenyl]trimethylsilane
2-(Trimethylsilylmethyl)-2-propenyl chloride
Silane, [2-(chloromethyl)-2-propen-1-yl]trimethyl-
2-(Chloromethyl)-3-trimethylsilyl-1-propene, 2-(Trimethylsilylmethyl)allyl chloride
[Molecular Formula]

C7H15ClSi
[MDL Number]

MFCD00013253
[MOL File]

18388-03-9.mol
[Molecular Weight]

162.73
Chemical PropertiesBack Directory
[Boiling point ]

162-163 °C/768 mmHg (lit.)
[density ]

0.899 g/mL at 25 °C (lit.)
[refractive index ]

n20/D 1.453(lit.)
[Fp ]

110 °F
[storage temp. ]

2-8°C
[solubility ]

Chloroform, Methanol (Slightly)
[form ]

Oil
[color ]

Clear Colourless
[Specific Gravity]

0.899
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[BRN ]

1747038
[Stability:]

Moisture Sensitive
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

10-36/37/38
[Safety Statements ]

26-36
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

3
[TSCA ]

No
[HazardClass ]

3.2
[PackingGroup ]

III
Hazard InformationBack Directory
[Uses]

2-??(Chloromethyl)??allyl-??trimethylsilane is one of the reagents to synthesize Leucasandrolide A Macrolide (I) via Mukaiyama aldol coupling.2-??(Chloromethyl)??allyl-??trimethylsilane was used in catalytic Sakurai reaction of a,??b-??enones.
Spectrum DetailBack Directory
[Spectrum Detail]

2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE(18388-03-9)1HNMR
2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE(18388-03-9)Raman
2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE(18388-03-9)FT-IR
2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE(18388-03-9)IR
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