| Identification | Back Directory | [Name]
[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) | [CAS]
18498-01-6 | [Synonyms]
ethane]dichlorocobalt(II)
[1,2-BIs(diphenylphosphino)
Dichloro[ethylenebis[diphenylphosphine]]cobalt
(1,2-bis(diphenylphosphino)ethane)-dichlorocobalt
1,2-[Bis(diphenylphosphino)ethane]cobaltdichloride
[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)
[1,2-Bis(diphenylphosphino)ethane]dichlorocobalt(Ⅱ)
[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]DICHLOROCOBALT(II)
[1,2-bis(diphenylphosphino)ethane]cobalt(II) chloride
1,2-Bis(diphenylphosphino)ethanedichlorocobalt(II),Min.97%
1,2-Bis(diphenylphosphino)ethanedichlorocobalt(II), min. 97%
1,2-Bis(diphenylphosphino)ethanedichlorocobalt(II),97% (DPPE)CoCl2 | [Molecular Formula]
C26H24Cl2CoP2 | [MDL Number]
MFCD00134173 | [MOL File]
18498-01-6.mol | [Molecular Weight]
528.26 |
| Chemical Properties | Back Directory | [Melting point ]
260 °C (dec.)(lit.)
| [storage temp. ]
Inert atmosphere,2-8°C | [form ]
Powder | [color ]
green | [Water Solubility ]
Insoluble in water. | [Sensitive ]
Hygroscopic | [InChI]
1S/C26H24P2.2ClH.Co/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2 | [InChIKey]
SYTWXWRJCLAZFP-UHFFFAOYSA-L | [SMILES]
Cl[Co]Cl.C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4 |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
20/21/22-36/37/38 | [Safety Statements ]
26-37/39 | [WGK Germany ]
3
| [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Questions And Answer | Back Directory | [Reactions]
- Catalyst used for the hydrovinylation of styrene.
- Cobalt-catalyzed hydroalkylation of [60] fullerene with active alkyl bromides.
- Cobalt-catalyzed 1,4-addition of organoboronic acids to activated alkenes.
|
| Hazard Information | Back Directory | [Uses]
Dichloro[bis(1,2-diphenylphosphino)ethane]cobalt(II) is used as a catalyst for regio- and stereoselective intermolecular enzyme coupling, cross-coupling reactions of alkyl halides with aryl Grignard reagents, hydrovinylation of styrene, tandem radical cyclization and cross-coupling, dimethylation, hydrodechlorination and addition reactions. | [reaction suitability]
core: cobalt
reagent type: catalyst |
|
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