| Identification | Back Directory | [Name]
(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE | [CAS]
185346-09-2 | [Synonyms]
Ι
aR*,8'
(3aS,8aR)-in-pybox
(-)-2,6-Bis[2-{3aS-(2(3'
2,6-BIS((3AS,8AR)-8H-INDENO(1,2-D)OXAZO&
aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine
2,6-Bis[(3aS,8aR)-(-)-8H-indeno[1,2-d]oxazolin-2-yl)]pyridine
2,6-Bis((3aS,8aR)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine
2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine
(3aS,3'aS,8aR,8'aR)-2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole
(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE
(3aS,3'aS,8aR,8'aR)-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole],99%e.e.
(-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine,97%
(-)-2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine, min. 97% Indenyl-PYBOX
(-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno [1,2-d]oxazole}]pyridine, min. 97%
(3aS,8aR)-in-pybox, (3aS,3μaS,8aR,8μaR)-2,2μ-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole
(-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aalpha,8aalpha)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine,min.97%
(-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aalpha:,8aalpha:)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine, min. 97%
Dimethlyammonium dichlorotri(μ-chloro)bis[(S)-(?)-2,2′-bis(dip-tolylphosphino)1,1′-binaphthyl]diruthenate(Ι | [Molecular Formula]
C25H19N3O2 | [MDL Number]
MFCD05861599 | [MOL File]
185346-09-2.mol | [Molecular Weight]
393.44 |
| Chemical Properties | Back Directory | [Melting point ]
265°C (dec.) | [alpha ]
-364.0° (c 1.04, CH2Cl2) | [Boiling point ]
633.0±55.0 °C(Predicted) | [density ]
1.50±0.1 g/cm3(Predicted) | [storage temp. ]
Sealed in dry,Room Temperature | [form ]
Powder | [pka]
4.35±0.20(Predicted) | [color ]
white to off-white | [Optical Rotation]
[α]20/D -375°, c = 1 in dichloromethane (typical) | [InChI]
1S/C25H19N3O2/c1-3-8-16-14(6-1)12-20-22(16)27-24(29-20)18-10-5-11-19(26-18)25-28-23-17-9-4-2-7-15(17)13-21(23)30-25/h1-11,20-23H,12-13H2/t20-,21-,22+,23+/m1/s1 | [InChIKey]
BZSJUFJXCHHRHW-LUKWVAJMSA-N | [SMILES]
C1(C2=N[C@@]3([H])C4=C(C=CC=C4)C[C@@]3([H])O2)=NC(C2=N[C@@]3([H])C4=C(C=CC=C4)C[C@@]3([H])O2)=CC=C1 |
| Hazard Information | Back Directory | [Chemical Properties]
White powder | [Uses]
Reactant involved in synthesis of:
- Chiral ruthenium(II)-pybox complexes for use as intramolecular C-H amination catalysts
- Bis(oxazolinyl_pyridine-scandium(III) triflate complex catalyst for enantioselective addition of pyrroles to indoles
- Chiral N,N,N-tridentate pybos and pyboxazine ligands
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| Questions And Answer | Back Directory | [Reaction]
- Ligand for Iridium-catalyzed enantio- and diastereoselective reductive aldol reactions
- Ligand for Scandium-catalyzed asymmetric Nazarov reactions
- Ligand for Scandium-catalyzed enantioselective pyrrole alkylations of α,β-unsaturated 2-acyl imidazoles
- Ligand for Scandium-catalyzed enantioselective Friedel-Crafts Alkylations
- Ligand for Nickel-catalyzed asymmetric cross-couplings of racemic propargyl groups with arylzinc reagents
- Ligand for Scandium-catalyzed enantioselective intramolecular carbonyl-ene reaction, the synthesis of (+)-triptophenolide
- Ligand for Scandium-catalyzed asymmetric synthesis of substituted 3-hydroxy-2-oxindoles
- Ligand for Indium-catalyzed enantio- and regioselective addition of pyrroles to isatins
- Ligand for Scandium-catalyzed asymmetric [3+2] annulation of allylsilanes with isatins in the synthesis of spirooxindoles
- Ligand for Scandium-catalyzed enantioselective allylation of isatins using allylsilanes
- Ligand for Scandium-catalyzed enantioselective carboannulation with allylsilanes
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| Company Name: |
LaaJoo Gold
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| Telephone: |
021-60702684 18516024827 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList20079/0_EN.htm |
| Company Name: |
J & K SCIENTIFIC LTD.
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| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
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021-61415566 800-8193336 |
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https://www.sigmaaldrich.cn |
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