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185449-80-3

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185449-80-3 Structure

185449-80-3 Structure
IdentificationBack Directory
[Name]

(R)-MONOPHOS
[CAS]

185449-80-3
[Synonyms]

MonoPhos
(R)-MONOPHOS
(S)-MONOPHOS
3,4- a′
97% (S)-MONOPHOS
]dinaphthalen-4-yl)dimethylamine
3,4- a']dinaphthalen-4-yl)dimethylamine 97%
3,4-a']dinaphthalen-4-yl)dimethylamine,min.97%(S)-MONOPHOS
Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine,N,N-diMet
(S)-N,N-DiMethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine
(11bS)-N,N-Dimethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
(S)-(+)-[4-N,N-Dimethylamino]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
(S)-(+)-[4-N,N-DIMETHYLAMINO]DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPINE
(R)-(-)-[4-N,N-DIMETHYLAMINO]DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPINE
(11bS)-N,N-Dimethyl-dinaphtho[2,1-d:1',2'-f][1,3,2] dioxaphosphepin-4-amine,99%e.e.
(R)-(-)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DI-NAPHTHALEN-4-YL)DIMETHYLAMINE
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DI-NAPHTHALEN-4-YL)DIMETHYLAMINE
(S)-(+)-[4-N,N-DIMETHYLAMINO]DINAPHTHO[2,1-D:1'',2''-F][1,3,2]DIOXAPHOSPHEPIN (S)-MONOPHOS
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 97% (S)-MONOPHOS
[Molecular Formula]

C22H18NO2P
[MDL Number]

MFCD03426988
[MOL File]

185449-80-3.mol
[Molecular Weight]

359.36
Chemical PropertiesBack Directory
[Melting point ]

190 °C (dec.)
[alpha ]

+587° (c 0.06, CHCl3)
[Boiling point ]

548.7±33.0 °C(Predicted)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

crystal
[pka]

1.22±0.20(Predicted)
[color ]

white
[Optical Rotation]

Consistent with structure
[Sensitive ]

moisture sensitive
[InChI]

InChI=1S/C22H18NO2P/c1-23(2)26-24-19-13-11-15-7-3-5-9-17(15)21(19)22-18-10-6-4-8-16(18)12-14-20(22)25-26/h3-14H,1-2H3
[InChIKey]

QCHAVHXSBZARBO-UHFFFAOYSA-N
[SMILES]

O1C2=CC=C3C(=C2C2=C4C(C=CC=C4)=CC=C2OP1N(C)C)C=CC=C3
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H412
[Precautionary statements ]

P273
[Safety Statements ]

22-24/25
[WGK Germany ]

3
[HS Code ]

2929.90.5090
[Storage Class]

11 - Combustible Solids
Questions and Answers (Q&A)Back Directory
[Uses]

1. Asymmetric hydrogenation of ketones and β-keto esters.
2. Light-induced, enantioselective hydrogenation.
Spectrum DetailBack Directory
[Spectrum Detail]

(R)-MONOPHOS(185449-80-3)1HNMR
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