| Identification | Back Directory | [Name]
TETRARHODIUM DODECACARBONYL | [CAS]
19584-30-6 | [Synonyms]
Dodecacarbonyltetrar
DODECACARBONYLTETRARHODIUM
TETRARHODIUM DODECACARBONYL
DODECACARBONYLTETRARHODIUM (0)
Tetrarhodium dodecacarbonyl,98%
Tetrarhodiumdodecacarbonyl,min.98%
Tetrarhodium dodecacarbonyl, min. 98%
tri-mu-carbonylnonacarbonyl-tetrahedro-tetrarhodium | [EINECS(EC#)]
243-171-9 | [Molecular Formula]
C12O12Rh4 | [MDL Number]
MFCD00016310 | [MOL File]
19584-30-6.mol | [Molecular Weight]
747.74 |
| Chemical Properties | Back Directory | [Appearance]
red to dark brown crystalline powder | [Melting point ]
150℃ [DOU83] | [density ]
2,52 g/cm3 | [storage temp. ]
Refrigerator (+4°C) | [solubility ]
reacts with H2O | [form ]
crystal | [color ]
dark red | [Specific Gravity]
2.52 | [Sensitive ]
air sensitive, light sensitive, store cold | [InChI]
1S/12CO.4Rh/c12*1-2;;;; | [InChIKey]
LVGLLYVYRZMJIN-UHFFFAOYSA-N | [SMILES]
[Rh].[Rh].[Rh].[Rh].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+] |
| Hazard Information | Back Directory | [Chemical Properties]
red to dark brown crystalline powder | [Uses]
Dodecacarbonyltetrarhodium is used as a catalyst for hydrogenation, hydroformylation, silylformylation, hydroboration, aldol reactions. | [Preparation]
Dodecacarbonyltetrarhodium is prepared from Tetracarbonyl(di-μ-chloro)dirhodium. | [reaction suitability]
core: rhodium
reagent type: catalyst | [storage]
Dodecacarbonyltetrarhodium is air sensitive; should be handled under nitrogen or argon; water
sensitive (decomposes to Rh6(CO)16 in the presence of water); heat sensitive; store in refrigerator under
carbon monoxide. Use in a fume hood. |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
20/21/22 | [Safety Statements ]
36 | [RIDADR ]
3089 | [WGK Germany ]
3 | [HazardClass ]
4.1 | [PackingGroup ]
III | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral |
|
| Company Name: |
J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Sigma-Aldrich
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021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
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Henan Alpha Chemical Co., Ltd.
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0371-55055611 18137792234 |
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Xi'an MC Biotech, Co., Ltd.
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