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1973375-72-2

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1973375-72-2 Structure

1973375-72-2 Structure
IdentificationBack Directory
[Name]

N]phenyl] iridium hexafluorophosphate, 98%
[CAS]

1973375-72-2
[Synonyms]

[5,5'-Bis(trifL
] iridium hexafL
Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6
(Ir[dF(CF3)ppy]2(5,5'-CF3bpy))PF6
(Ir[dF(CF3)ppy]2(5,5'-CF3bpy))PF6
)-2,2'-bipyridine-κN,κN]bis[3,5-difL
N]phenyl] iridium hexafluorophosphate, 98%
5,5’-Bis(trifluoromethyl)-2,2’-bipyridine-κN,κN]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl]Iridium Hexafluorophosphate
[5,5'-Bis(trifluoromethyl)-2,2'-bipyridine-κN,κN]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl] iridium hexafluorophosphate
[5,5''-Bis(trifluoromethyl)-2,2''-bipyridine-κN,κN]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl] iridium hexafluorophosphate
[5,5'-Bis(trifluoromethyl)-2,2'-bipyridine-κN,κN]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl] iridium hexafluorophosphate[[Ir(dFCF3ppy)2-(5,5'-dCF3bpy)]PF6]
5,5'-Bis(trifluoromethyl)-2,2'-bipyridine-κN,κN]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl] iridium hexafluorophosphate,N]phenyl] iridium hexafluorophosphate,Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6
[Molecular Formula]

C36H16F22IrN4P
[MOL File]

1973375-72-2.mol
[Molecular Weight]

1145.71
Chemical PropertiesBack Directory
[Melting point ]

>300 °C
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

powder or crystals
[Appearance]

Light yellow to yellow Solid
[InChIKey]

FVILJAKEZXOYPD-UHFFFAOYSA-N
[SMILES]

[Ir+](c5c(c(cc(c5)F)F)c6ncc(cc6)C(F)(F)F)c3c(c(cc(c3)F)F)c4ncc(cc4)C(F)(F)F.FC(F)(F)c1cnc(cc1)c2ncc(cc2)C(F)(F)F.F[P-](F)(F)(F)(F)F
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P280-P301+P312-P302+P352-P305+P351+P338
[WGK Germany ]

WGK 3
[Storage Class]

11 - Combustible Solids
Hazard InformationBack Directory
[Uses]

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations including the alkylation of remote C-H bonds and alkene aminoarylation.
[reaction suitability]

reaction type: Photocatalysis
reagent type: catalyst
Spectrum DetailBack Directory
[Spectrum Detail]

N]phenyl] iridium hexafluorophosphate, 98%(1973375-72-2)1HNMR
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