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199465-66-2

199465-66-2 Structure

199465-66-2 Structure
IdentificationBack Directory
[Name]

2-CYANOBENZYLZINC BROMIDE
[CAS]

199465-66-2
[Synonyms]

2-CyanobenzyL
2-CYANOBENZYLZINC BROMIDE
(2-cyanobenzyl)zinc(II) broMide
2-cyanobenzylzinc bromide solution
2-Cyanobenzylzinc bromide solution 0.5 in THF
2-Cyanobenzylzinc bromide solution 0.5M in THF
2-Cyanobenzylzinc bromide 0.5 M in Tetrahydrofuran
2-CYANOBENZYLZINC BROMIDE, 0.5M SOLUTION IN TETRAHYDROFURAN
[Molecular Formula]

C8H6BrNZn
[MDL Number]

MFCD01311397
[MOL File]

199465-66-2.mol
[Molecular Weight]

261.43
Chemical PropertiesBack Directory
[density ]

0.993 g/mL at 25 °C
[Fp ]

1 °F
[storage temp. ]

2-8°C
Safety DataBack Directory
[Hazard Codes ]

F,Xn
[Risk Statements ]

14-19-22-36/38-40-36/37-11
[Safety Statements ]

16-26-33-36-36/37
[RIDADR ]

UN 2056 3/PG 2
[WGK Germany ]

1
Hazard InformationBack Directory
[Uses]

2-Cyanobenzylzinc bromide can be used as a reactant:
  • In the metal-catalyzed Negishi cross-coupling reactions to prepare aryl or heteroaryl derivatives via carbon-carbon bond formation.
  • To synthesize 4-(2-Cyanobenzyl)-3′-(trifluoromethyl)biphenyl by reacting with aryl nonaflate in the presence of Pd(dba)2 as a catalyst.
  • To prepare 2-[(2-cyanophenyl)methyl] benzamide by treating with 2-iodobenzamide using a nickel catalyst.

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