| Identification | Back Directory | [Name]
SLAP 5-TMS | [CAS]
2084112-39-8 | [Synonyms]
SLAP 5-TMS TM
SLAP 5-TMS TM >=95%
Ethanamine, 2-[[bis(trimethylsilyl)methyl]thio]- | [Molecular Formula]
C9H25NSSi2 | [MOL File]
2084112-39-8.mol | [Molecular Weight]
235.54 |
| Hazard Information | Back Directory | [Uses]
When used with aliphatic or aromatic aldehydes, this silicon amine protocol SLAP reagent enables the photomediated synthesis of thiomorpholines and thiazepanes. For photocatalytic cross-coupling with this SLAP Reagent, Ir[(ppy)2dtbbpy]PF6 (747769) is used with a recommended starting combination of Lewis acids Bi(OTf)3 (633305) and Cu(OTf)2 (283673) prior to subsequent substrate-specific optimization. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents and is well-suited for scale-up reactions. |
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