| Identification | Back Directory | [Name]
DIISOPROPYL 2-((TOSYLOXY)IMINO)MALONATE | [CAS]
2103906-28-9 | [Synonyms]
DIISOPROPYL 2-((TOSYLOXY)IMINO)MALONATE
Propanedioic acid, 2-[[[(4-methylphenyl)sulfonyl]oxy]imino]-, 1,3-bis(1-methylethyl) ester | [Molecular Formula]
C16H21NO7S | [MOL File]
2103906-28-9.mol | [Molecular Weight]
371.41 |
| Hazard Information | Back Directory | [Uses]
As demonstrated by Laszlo Kürti′s lab, ketomalonate oxime O-sulfonates act as doubly N-electrophilic linchpin reagents towards strong C-nucleophiles such as alkyl- and arylmetals (e.g., Grignard reagents). Thus, symmetrical dialkyl- as well as diarylamines may be directly prepared at low tempretatures and in the absence of transition metal catalysts. Other ketomalonate oxime O-sulfonates include 902705, 902624, and 902748 |
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