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212143-24-3

212143-24-3 Structure

212143-24-3 Structure
IdentificationBack Directory
[Name]

DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II)
[CAS]

212143-24-3
[Synonyms]

DICHLORO[(S)-BINAP][(S)-DAIPEN]RUTHENIUM(II)
Dichlorobisdiphenylphosphinobinaphthylbismethoxyphenylmethylbutanediam
dichloro[(s)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(2s)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediami
DICHLORO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(2S)-(+)-1,1-BIS(4-METHOXYPHENYL)-3-METHYL-1,2-BUTANEDIAMINE]
DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II)
DICHLORO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1-BINAPHTHYL][(2S)-(+)-1,1-BIS(4-METHOXYPHENYL)-3-METHYL-1,2-BUTANEDIAMINE]RUTHENIUM(II)
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)dichloromethaneadduct,min.97%
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) dichloromethane adduct, min. 97%
[Molecular Formula]

C63H58Cl2N2O2P2Ru
[MDL Number]

MFCD02684564
[MOL File]

212143-24-3.mol
[Molecular Weight]

1109.07
Chemical PropertiesBack Directory
[Melting point ]

>100°C
[storage temp. ]

0-6°C
[form ]

Powder
[color ]

white to pale yellow
[Sensitive ]

air sensitive, store cold
Safety DataBack Directory
[Safety Statements ]

22-24/25
Questions and Answers (Q&A)Back Directory
[Reactions]

The NOYORI catalysts are a ruthenium-based system containing a phosphine and 1,2-diamine ligand. The catalysts are used in the highly-efficient, enantio and diastereoselective hydrogenation of simple ketones, usually under the mild conditions of room temperature and 1-10 atm of hydrogen pressure. Reactions of 212143-24-3
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