ChemicalBook--->CAS DataBase List--->212378-89-7

212378-89-7

212378-89-7 Structure

212378-89-7 Structure
IdentificationBack Directory
[Name]

(1S,2R)-1-(2-(HYDROXY-3,5-DI-TERT-BUTYL&
[CAS]

212378-89-7
[Synonyms]

(1S,2R)-1-(2-(HYDROXY-3,5-DI-TERT-BUTYL&
(1S,2R)-1-[(3,5-Di-tert-butyl-2-hydroxybenzylidene)amino]-2-...
(1S,2R)-1-[(3,5-Di-tert-butyl-2-hydroxybenzylidene)amino]-2-indanol 97%
(1S,2R)-1-((3,5-Di-tert-butyl-2-hydroxybenzylidene)amino)-2,3-dihydro-1H-inden-2-ol
1H-Inden-2-ol, 1-[[[3,5-bis(1,1-dimethylethyl)-2-hydroxyphenyl]methylene]amino]-2,3-dihydro-, (1S,2R)-
[Molecular Formula]

C24H31NO2
[MDL Number]

MFCD07369724
[MOL File]

212378-89-7.mol
[Molecular Weight]

365.51
Chemical PropertiesBack Directory
[Melting point ]

128-131 °C
[form ]

solid
[InChI]

1S/C24H31NO2/c1-23(2,3)17-11-16(22(27)19(13-17)24(4,5)6)14-25-21-18-10-8-7-9-15(18)12-20(21)26/h7-11,13-14,20-21,26-27H,12H2,1-6H3/b25-14+/t20-,21+/m1/s1
[InChIKey]

MMNHXVSQIRTBOZ-FOYRYCBESA-N
[SMILES]

CC(C)(C)c1cc(\C=N\[C@@H]2[C@H](O)Cc3ccccc23)c(O)c(c1)C(C)(C)C
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

(1S,2R)-1-[(3,5-Di-tert-butyl-2-hydroxybenzylidene)amino]-2-indanol can be used as a ligand to prepare Schiff-base chromium(III) complex, which is used as a catalyst in the synthesis of:
  • Poly(cyclohexene carbonate) by coupling of CO2 and cyclohexene oxide.
  • β-hydroxyenol ethers by asymmetric hetero-ene reaction between aryl aldehydes and 2-methoxypropene.

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