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213843-90-4

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213843-90-4 Structure

213843-90-4 Structure
IdentificationBack Directory
[Name]

(3AR,8AR)-(-)-(2,2-DIMETHYL-4,4,8,8-TETRAPHENYL-TETRAHYDRO-[1,3]DIOXOLO[4,5-E][1,3,2]DIOXAPHOSPHEPIN-6-YL)DIMETHYLAMINE
[CAS]

213843-90-4
[Synonyms]

(3aR,8AR)-(-)-(2,2-DIMETHYL-4,4,8,8-TET&
(3AR,8aR)-N,N,2,2-Tetramethyl-4,4,8,8-tetraphenyltetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxapho
(3AR,8aR)-N,N,2,2-Tetramethyl-4,4,8,8-tetraphenyltetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosph
(3aR,8aR)-N,N,2,2-Tetramethyl-4,4,8,8-tetraphenyltetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-amine
(3aR,8aR)-Tetrahydro-N,N,2,2-tetramethyl-4,4,8,8-tetraphenyl-1,3-dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-amine
(3aR,8aR)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine
(3AR,8AR)-(-)-(2,2-DIMETHYL-4,4,8,8-TETRAPHENYL-TETRAHYDRO-[1,3]DIOXOLO[4,5-E][1,3,2]DIOXAPHOSPHEPIN-6-YL)DIMETHYLAMINE
(11aR)-(+)-10,11,12,13-Tetrahydro-5-(1,1-diMethylethyl)diindeno[7,1-de,1',7'-fg)[1.3.2] dioxaphosphocin, 97% (R)-FuP-tBu
(3aR,8aR)-(-)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine,98%
(3aR,8aR)-(-)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine 96%
(3aR,8aR)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro- [1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6- yl)dimethylamine,99%e.e.
(3aR,8aR)-(-)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine,min.98%
(3aR,8aR)-(-)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine, min. 98%
(3aR,8aR)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro- [1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6- yl)dimethylamine (3aR,8aR)-(2,2-
(3aR,8aR)-(-)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-
e][1,3,2]dioxaphosphepin-6-yl)dimethylamine, min. 98%
[Molecular Formula]

C33H34NO4P
[MDL Number]

MFCD04117685
[MOL File]

213843-90-4.mol
[Molecular Weight]

539.6
Chemical PropertiesBack Directory
[Melting point ]

218-221 °C
[alpha ]

-159° (c 1.66, CHCl3)
[Boiling point ]

569.8±50.0 °C(Predicted)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

Powder
[pka]

2.44±0.70(Predicted)
[color ]

white
[Sensitive ]

moisture sensitive
[InChIKey]

DRPNADVMTMEWQY-LOYHVIPDSA-N
[SMILES]

CN(C)P1OC([C@@H]2OC(C)(C)O[C@H]2C(O1)(c3ccccc3)c4ccccc4)(c5ccccc5)c6ccccc6
Safety DataBack Directory
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reaction]

  1. Monodendate ligand for the enantioselective intramolecular reaction of prochiral cyclohexadienones.
  2. Ligand use in the palladium-catalyzed, enantioselective diboration of allenes.
  3. Enantioselective Rh-catalyzed [2+2+2] cycloaddition of alkynes and isocyanates.
  4. Palladium-catalyzed enantioselective C-H arylation.
  5. Palladium-catalyzed dynamic kinetic cross-coupling.
  6. Palladium-catalyzed enantioselective C-H arylation.
Reactions of 213843-90-4_1
Reactions of 213843-90-4_2
Hazard InformationBack Directory
[Uses]

DSM MonoPhos Family of Highly Efficient Privileged Ligands
Spectrum DetailBack Directory
[Spectrum Detail]

(3AR,8AR)-(-)-(2,2-DIMETHYL-4,4,8,8-TETRAPHENYL-TETRAHYDRO-[1,3]DIOXOLO[4,5-E][1,3,2]DIOXAPHOSPHEPIN-6-YL)DIMETHYLAMINE(213843-90-4)1HNMR
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