| Identification | Back Directory | [Name]
3-chloro-1-(1,1-dimethylethyl)Naphthalene | [CAS]
2217657-09-3 | [Synonyms]
1-(tert-butyl)-3-chloronaphthalene
3-chloro-1-(1,1-dimethylethyl)Naphthalene | [Molecular Formula]
C14H15Cl | [MOL File]
2217657-09-3.mol | [Molecular Weight]
218.72 |
| Chemical Properties | Back Directory | [Boiling point ]
300.1±11.0 °C(Predicted) | [density ]
1.081±0.06 g/cm3(Predicted) | [InChI]
InChI=1S/C14H15Cl/c1-14(2,3)13-9-11(15)8-10-6-4-5-7-12(10)13/h4-9H,1-3H3 | [InChIKey]
ALECXKNDPPUBFP-UHFFFAOYSA-N | [SMILES]
C1(C(C)(C)C)=C2C(C=CC=C2)=CC(Cl)=C1 |
| Hazard Information | Back Directory | [Uses]
3-chloro-1-(1,1-dimethylethyl)Naphthalene, also known as 1-(tert-butyl)-3-chloronaphthalene, is a key intermediate in the synthesis process of organic electroluminescent diodes (OLED) molecular materials. | [Preparation]
In a three-neck flask, the catalyst ligand 1-(2-carboxyethyl)-3-formyltriacyl-1H-imidazol-3-ammonium chloride (1.03 mmol), nickel acetylacetonate (1.01 mmol), and lithium tert-butoxide (31.2 mmol) were added to tetrahydrofuran (100 mL). Isopropyl magnesium chloride (14.6 mL, 1.7 M ether solution, 24.8 mmol) was subsequently added under nitrogen protection and agitation. Add 1-bromo-3-chloronaphthalene after 0.5 h and stir at 0 °C for 2 h. Finally, 3-chloro-1-(1,1-dimethylethyl)Naphthalene was obtained after purification.
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