| Identification | Back Directory | [Name]
TRANS-DIBROMOBIS(TRIPHENYLPHOSPHINE)- | [CAS]
22180-53-6 | [Synonyms]
Pd13.4%
TRANS-DIBROMOBIS(TRIPHENYLPHOSPHINE)-
Dibromo bis(triphenylphosphine) palladium (II)
trans-Dibromobis(triphenylphosphine)palladium(II), Pd
trans-Dibromobis(triphenylphosphine)palladium(II), Pd 13.4% | [Molecular Formula]
[(C6H5)3P]2PdBr2 | [MDL Number]
MFCD00134175 | [MOL File]
22180-53-6.mol | [Molecular Weight]
790.8 |
| Chemical Properties | Back Directory | [Appearance]
orange solid | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [solubility ]
Soluble in chloroform, toluene and benzene | [form ]
Powder | [color ]
yellow | [Sensitive ]
Hygroscopic | [InChI]
1S/2C18H15P.2BrH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2 | [InChIKey]
MCSDDEAMPOYJJI-UHFFFAOYSA-L | [SMILES]
Br[Pd]Br.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6 |
| Hazard Information | Back Directory | [Chemical Properties]
orange solid | [Uses]
Catalyst for:
- Equilibrium palladation of alkanes and arenes and functionalization of hydrocarbons
Reactant for:
- Homocoupling reactions induced by P-C reductive elimination
- Preparation of palladium imidazolylidene complexes via Suzuki coupling reactions
| [reaction suitability]
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst |
|
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