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228121-39-9

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228121-39-9 Structure

228121-39-9 Structure
IdentificationBack Directory
[Name]

(-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE
[CAS]

228121-39-9
[Synonyms]

[(R,R)Ethyl-DuPhosRh(COD)]BF4
(-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE
1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
(-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
(-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I)tetrafluoroborate,98+%(R,R)-Et-DUPHOS-Rh
(-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate (R,R)-Et-DUPHOS-Rh
(-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (R,R)-Et-DUPHOS-Rh
[Molecular Formula]

C30H48BF4P2Rh-
[MDL Number]

MFCD03412155
[MOL File]

228121-39-9.mol
[Molecular Weight]

660.36
Chemical PropertiesBack Directory
[form ]

Powder
[color ]

Orange to red to brown
[Sensitive ]

air sensitive
[CAS DataBase Reference]

228121-39-9
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P280-P304+P340+P312-P337+P313-P403+P233
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
[HS Code ]

29310099
Questions And AnswerBack Directory
[Reaction]

  1. Ligand used in asymmetric hydrogenation of 2-methylenesuccinamic acid.
  2. Ligand used for the Rh-catalyzed asymmetric hydrogenation of α-aminomethylacrylates.
Reactions of 228121-39-9
Hazard InformationBack Directory
[Uses]

(-)-1,2-Bis(2R,5R-2,5-diethylphospholano)benzene)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is a rhodium-based catalyst which is used in asymmetric hydrogenation reactions.
[Uses]

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Catalyst for:
  • Asymmetric hydrogenation reactions
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