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229184-99-0

229184-99-0 Structure

229184-99-0 Structure
IdentificationBack Directory
[Name]

(S,S)-(-)-1,2-DI(1-NAPHTHYL)-1,2-ETHANEDIOL
[CAS]

229184-99-0
[Synonyms]

(S,S)-1,2-DI(1-NAPHTHYL)-1,2-ETHANEDIOL
(S,S)-(-)-1,2-DI(1-NAPTHYL)-1,2-ETHANEDIOL
(S,S)-(-)-1,2-DI(1-NAPHTHYL)-1,2-ETHANEDIOL
1,2-Ethanediol, 1,2-di-1-naphthalenyl-, (1S,2S)-
[Molecular Formula]

C22H18O2
[MDL Number]

MFCD01863520
[MOL File]

229184-99-0.mol
[Molecular Weight]

314.38
Chemical PropertiesBack Directory
[Melting point ]

149-151 °C (lit.)
[optical activity]

[α]23/D 25°, c = 1 in chloroform
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

(S, S)-(-)-1,2-Di(1-naphthyl)-1,2-ethanediol can be used as:
  • A ligand in the asymmetric sulfoxidation of dihydrothienopyrimidine.
  • A reactant for the preparation of (2S,2′S)-[(1S,2S)-1,2-bis(naphthalen-1-yl)ethane-1,2-diyl] bis[2-(dimethylamino)propanoate], a chiral bisester ligand via condensation reaction with N,N-dimethylamino acid using aldol-Tishchenko condensation catalyst.
  • A reactant to synthesize diol-SnCl4 chiral Bronsted acid complex, which is employed as a catalyst in the allylboration of aldehydes.

Spectrum DetailBack Directory
[Spectrum Detail]

(S,S)-(-)-1,2-DI(1-NAPHTHYL)-1,2-ETHANEDIOL(229184-99-0)IR
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