| Identification | Back Directory | [Name]
TETRABUTYLAMMONIUM TETRABUTYLBORATE | [CAS]
23231-91-6 | [Synonyms]
TETRABUTYLAMMONIUM TETRABUTYLBORATE
etrabutylazanium,tetrabutylboranuide
tetrabutylazanium:tetrabutylboranuide
Tetrabutylammonium tetrabutylborate 97%
TETRA(N-BUTYL)AMMONIUM TETRA(N-BUTYL)BORATE | [Molecular Formula]
C32H72BN | [MDL Number]
MFCD00061526 | [MOL File]
23231-91-6.mol | [Molecular Weight]
481.73 |
| Chemical Properties | Back Directory | [Melting point ]
106-109 °C(lit.)
| [form ]
Powder | [color ]
White | [BRN ]
4171555 | [InChI]
1S/C16H36B.C16H36N/c2*1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4/h2*5-16H2,1-4H3/q-1;+1 | [InChIKey]
LUQGURIOJLNCGE-UHFFFAOYSA-N | [SMILES]
CCCC[B-](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC |
| Hazard Information | Back Directory | [Uses]
Tetrabutylammonium tetrabutylborate can be used as:
- A mild reducing agent to synthesize oxovanadium reduced cluster.
- A co-initiator in radical photopolymerization of trimethylolpropane triacrylate in the presence of dyes with diazine structure.
| [Purification Methods]
Dissolve it in MeOH or acetone, and crystallise by adding distilled water. It also crystallises from EtOH or EtOAc. Dry it in a vacuum at 70o. It has also been successively recrystallised from isopropyl ether, isopropyl ether/acetone (50:1) and isopropyl ether/EtOH (50:1) for 10hours, then isopropyl ether/acetone for 1hour, and dried at 65o under reduced pressure for 1 week. [Kondo et al. J Chem Soc, Faraday Trans 1 76 812 1980, Beilstein 4 III 293, 4 III 558.] |
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