| Identification | Back Directory | [Name]
Chloromethyl Trimethylsilyl Ether | [CAS]
23586-77-8 | [Synonyms]
(Chloromethoxy)trimethylsilane
Silane, (chloromethoxy)trimethyl-
Chloromethyl Trimethylsilyl Ether | [Molecular Formula]
C4H11ClOSi | [MDL Number]
MFCD17013366 | [MOL File]
23586-77-8.mol | [Molecular Weight]
138.67 |
| Hazard Information | Back Directory | [Preparation]
Chloromethyl Trimethylsilyl Ether is prepared in situ under nitrogen by addition of a cooled (-78 °C) solution of Sulfuryl
Chloride (1 equiv) in dry dichloromethane (2 M) to a solution of ethyl (trimethylsilyloxy)methyl sulfide in
dichloromethane (1 M)[1]. | [storage]
Chloromethyl Trimethylsilyl Ether is low stability; best prepared in situ at low temperature. | [References]
1. Gundersen, L.-L.; Benneche, T. ACS 1991, 45, 975. |
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