ChemicalBook--->CAS DataBase List--->24720-64-7

24720-64-7

24720-64-7 Structure

24720-64-7 Structure
IdentificationBack Directory
[Name]

2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE
[CAS]

24720-64-7
[Synonyms]

2-(TRIPHENYLPHOSPHOR
2-(triphenylphosphoranylidene)
1-Formylethylidenetriphenylphosphorane
2-(Triphenylphosphoranylidene)propanal
2-(triphenyl-l5-phosphanylidene)propanal
Propanal,2-(triphenylphosphoranylidene)-
2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE
2-(Triphenylphosphoranylidene)propionaldehyde 98%
2-(triphenylphosphoranylidene)propionaldehyde, 98 %
[Molecular Formula]

C21H19OP
[MDL Number]

MFCD00075596
[MOL File]

24720-64-7.mol
[Molecular Weight]

318.35
Chemical PropertiesBack Directory
[Appearance]

White to light beige crystalline powder
[Melting point ]

219-221 °C(lit.)
[Boiling point ]

478.5±28.0 °C(Predicted)
[density ]

1.14±0.1 g/cm3(Predicted)
[storage temp. ]

Inert atmosphere,Store in freezer, under -20°C
[form ]

Low Melting Solid
[color ]

White to pink to brown
[InChI]

InChI=1S/C21H19OP/c1-18(17-22)23(19-11-5-2-6-12-19,20-13-7-3-8-14-20)21-15-9-4-10-16-21/h2-17H,1H3
[InChIKey]

VHUQEFAWBCDBSC-UHFFFAOYSA-N
[SMILES]

C(=O)C(=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1)C
[CAS DataBase Reference]

24720-64-7
Hazard InformationBack Directory
[Chemical Properties]

White to light beige crystalline powder
[Uses]

Reactant for:• ;Preparation of acitretin analogs with antitumor activity1• ;Stereoselective synthesis of essential building blocks of phorboxazole A via hetero Diels-Alder and stereoselective hetero-Michael addition/equilibration2• ;Preparation of C1-C14 fragment of sarcoglaucol-16-one via Z-selective ando-type Horner-Wadsworth-Emmons olefination3• ;Wittig reactions4• ;Synthesis of ring-expanded and epothilone-hybridized macrosphelide analogs as apoptosis-inducing agents5• ;Preparation of phosphonic acid-containing analogs of mycophenolic acid as inhibitors
[reaction suitability]

reaction type: C-C Bond Formation
Safety DataBack Directory
[Risk Statements ]

22-36/37/38
[Safety Statements ]

26-37/39
[WGK Germany ]

3
[HS Code ]

29319090
Spectrum DetailBack Directory
[Spectrum Detail]

2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE(24720-64-7)1HNMR
2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE(24720-64-7)Raman
2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE(24720-64-7)IR
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