ChemicalBook--->CAS DataBase List--->251922-46-0

251922-46-0

251922-46-0 Structure

251922-46-0 Structure
IdentificationBack Directory
[Name]

3-Oxetaneethanol
[CAS]

251922-46-0
[Synonyms]

3-Oxetaneethanol
2-(oxetan-3-yl)ethano
2-(3-Oxetanyl)ethanol
2-(oxetan-3-yl)ethanol
2-(oxetan-3-yl)ethan-1-ol
3-(2-Hydroxyethyl)oxetane
3-Oxetaneethanol ISO 9001:2015 REACH
[Molecular Formula]

C5H10O2
[MDL Number]

MFCD17215859
[MOL File]

251922-46-0.mol
[Molecular Weight]

102.13
Chemical PropertiesBack Directory
[Boiling point ]

206℃
[density ]

1.051
[Fp ]

96℃
[storage temp. ]

Sealed in dry,2-8°C
[pka]

14.95±0.10(Predicted)
[Appearance]

Colorless to light yellow Liquid
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Skull and Crossbones (GHS06)
GHS05,GHS06
[Signal word ]

Danger
[Hazard statements ]

H227-H301-H315-H318-H412
[Precautionary statements ]

P261-P280-P301+P310-P305+P351+P338
[RIDADR ]

UN1993
[HS Code ]

2905599890
Spectrum DetailBack Directory
[Spectrum Detail]

3-Oxetaneethanol(251922-46-0)1HNMR
Hazard InformationBack Directory
[Synthesis]

3-[2-(Benzyloxy)ethyl]oxetane

569678-81-5

3-Oxetaneethanol

251922-46-0

Step D: A mixed system of 3-[2-(benzyloxy)ethyl]oxetane (550 mg, 2.86 mmol), Pd/C catalyst (350 mg), and anhydrous ethanol (5 mL) was subjected to a hydrogen atmosphere and stirred at room temperature for 48 hours. Upon completion of the reaction, the catalyst was removed by filtration and the filtrate was concentrated under reduced pressure to afford the target product 2-(oxetan-3-yl)ethanol (200 mg, 1.96 mmol, 66% yield) as a colorless oily liquid.

[References]

[1] Journal of the American Chemical Society,
[2] Journal of the American Chemical Society, 2009, vol. 131, p. 2786 - 2787
[3] Patent: WO2015/142903, 2015, A2. Location in patent: Page/Page column 93
[4] Patent: WO2015/140133, 2015, A1. Location in patent: Page/Page column 104; 105
[5] Chemical and Pharmaceutical Bulletin, 1999, vol. 47, # 9, p. 1334 - 1337
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