| Identification | Back Directory | [Name]
Bromo(o-tolyl)bis(triethylphosphine)nickel(II) | [CAS]
26521-33-5 | [Synonyms]
Bromo(o-tolyl)bis(triethylphosphine)nickel(II) | [Molecular Formula]
C19H40BrNiP2 | [MDL Number]
MFCD16876518 | [MOL File]
26521-33-5.mol | [Molecular Weight]
469.07 |
| Chemical Properties | Back Directory | [Melting point ]
mp 102-103 °C | [solubility ]
sol benzene, diethyl ether, THF, DMF, ethanol, DMSO, acetone, cyclohexane, cumene, nitromethane, dichloromethane. |
| Hazard Information | Back Directory | [Uses]
Bromo(o-tolyl)bis(triethylphosphine)nickel(II) can be used for Ullmann and cross-coupling reactions; halogen exchange of aryl and vinyl halides; and oligomerization reactions. | [Preparation]
Bromo(o-tolyl)bis(triethylphosphine)nickel(II) is prepared in 67% yield by treating a benzene solution of dibromobis(triethylphosphine)nickel(II) with an ethereal solution of o-tolylmagnesium bromide. | [storage]
Although no special precautions are reported, this complex is likely to be toxic, as with many nickel reagents. |
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