| Identification | Back Directory | [Name]
2,3,4,9-Tetrahydro-1,2-dimethyl-1H-pyrido[3,4-b]indole | [CAS]
27297-47-8 | [Synonyms]
Leptocladine 2,3,4,9-Tetrahydro-1,2-dimethyl-1H-pyrido[3,4-b]indole 1H-Pyrido[3,4-b]indole, 2,3,4,9-tetrahydro-1,2-dimethyl- (9CI) | [Molecular Formula]
C13H16N2 | [MOL File]
27297-47-8.mol | [Molecular Weight]
200.28 |
| Hazard Information | Back Directory | [Description]
First isolated from A rthrophy tum leptocladum M. Pop. by Yurashevskii, this alkaloid was assigned the empirical formula C13H16N2, later altered to that given
above when its structure as 3:4-dimethyl-3:4:5:6-tetrahydrocarboline was determined. Of that crystalline salts that have been prepared, the hydrochloride has
m.p. 234-5°C (dec.); methiodide, m.p. 227 -SoC; platinichloride, orange
crystals, m.p. 197 -SoC (dec.); dipicrate, m.p. lSI-2°C and the monopicrate
which exists in two forms, m.p. l12-4°C from aqueous solutions and m.p.
l76-7°C from EtOH. The alkaloid has been synthesized by condensation of
dipterine with formaldehyde in the presence of dilute H2S04 , | [References]
Yurashevskii., J. Gen. Chern., USSR, 9,545 (1939)
Yurashevskii., ibid, 11,157 (1941) |
|
|