| Identification | Back Directory | [Name]
(+)-ISOPINOCAMPHEOL | [CAS]
27779-29-9 | [Synonyms]
Nsc167499
3-PINANOL
(+)-ISOPINOCAMPHEOL
(+)-Isopinocampheol
ISOPINOCAMPHEOL, (+)-
3-Pinanol, stereoisomer
ISOPINOCAMPHEOL, (-)-(SG)
(1S,2S,3S,5R)-(+)-IsopinocaMpheol 98%
(1s,2s,3s,5r)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-ol
(1S,3R,4R,5R)-4,6,6-trimethylbicyclo[3.1.1]heptan-3-ol
Bicyclo[3.1.1]heptan-3-ol, 2,6,6-trimethyl-, (1R,2R,3R,5S)-rel-
(1S,2S,3S,5R)-3-Pinanol, (1S,2S,3S,5R)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol
Bicyclo[3.1.1]heptan-3-ol, 2,6,6-trimethyl-, (1.alpha.,2.beta.,3.alpha.,5.alpha.)-
(1S,2S,3S,5R)-3-Pinanol, 3-Pinanol, (1S,2S,3S,5R)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol | [EINECS(EC#)]
248-657-4 | [Molecular Formula]
C10H18O | [MDL Number]
MFCD00074780 | [MOL File]
27779-29-9.mol | [Molecular Weight]
154.25 |
| Chemical Properties | Back Directory | [Melting point ]
52-55 °C | [Boiling point ]
219 °C(lit.) | [density ]
0.8389 (rough estimate) | [refractive index ]
1.4710 (estimate) | [Fp ]
93 °C | [form ]
solid | [pka]
15.35±0.60(Predicted) | [Optical Rotation]
[α]20/D +35.1°, c =20 in ethanol | [LogP]
2.805 (est) |
| Hazard Information | Back Directory | [Uses]
(1S,2S,3S,5R)-(+)-Isopinocampheol may be used in the preparation of
- thermotropic chiral nematic side-chain copolymers
- ortho-(diphenylphosphino)phenylphosphonous acid di[(1S,2S,3S,5R)-2,6,6-trimethyl-bicyclo[3.1.1]-hept-3-yl]ester, a phosphino-phosphonite ligand
- O,O′bis[(1S,2S,3S,5R)2,6,6-trimethylbicyclo[3.1.1]hept-3-yl] dithiophosphoric acid, a bioactive compound with antifungal effect
| [General Description]
(1S,2S,3S,5R)-(+)-Isopinocampheol is a chiral terpenol. | [Purification Methods]
Dissolve it in Et2O, dry over MgSO4, filter, evaporate, then recrystallise it from pet ether. Also recrystallise it from aqueous EtOH and distil it in a vacuum. [Kergomard & Geneix Bull Soc Chim Fr 394 1958, Zweifel & Brown J Am Chem Soc 86 393 1964.] The 3,4-dinitrobenzoyl derivative has m 100-101o, the phenylcarbamoyl derivative has m 137-138o and the acid -phthalate has m 125-126o. [Beilstein 6 III 282, 283.] |
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