| Identification | Back Directory | [Name]
1-IODO-4-(PENTAFLUOROSULFANYL)BENZENE | [CAS]
286947-68-0 | [Synonyms]
4-Pentafluorosulfur iodobenzene
4-IODOPHENYLSULFUR PENTAFLUORIDE
4-IODOPHENYLSULPHUR PENTAFLUORIDE
10Iodo-4-(pentafluorothio)benzene
PENTAFLUORO-(4-IODOPHENYL)-SULFUR
1-IODO-4-(PENTAFLUOROTHIO)BENZENE
4-IodophenylsulfurPentafluoride>
1-IODO-4-(PENTAFLUOROSULFANYL)BENZENE
Sulfur, pentafluoro(4-iodophenyl)-, (OC-6-21)-
1-Iodo-4-(pentafluorothio)benzene, 1-Iodo-4-(pentafluorosulphanyl)benzene | [Molecular Formula]
C6H4F5IS | [MDL Number]
MFCD03788514 | [MOL File]
286947-68-0.mol | [Molecular Weight]
330.06 |
| Chemical Properties | Back Directory | [Melting point ]
36 °C | [Boiling point ]
52 °C / 0.8mmHg | [storage temp. ]
Refrigerator | [solubility ]
soluble in Toluene | [form ]
powder to crystal | [color ]
Light orange to Yellow to Green | [InChI]
InChI=1S/C6H4F5IS/c7-13(8,9,10,11)6-3-1-5(12)2-4-6/h1-4H | [InChIKey]
FRYANWYSCROOCU-UHFFFAOYSA-N | [SMILES]
S(F)(F)(F)(F)(F)C1C=CC(I)=CC=1 | [CAS DataBase Reference]
286947-68-0 |
| Hazard Information | Back Directory | [Preparation]
To a solution of 4-(pentafluorothio)aniline (15.0 g, 68.4 mmol) and ice (40.0 g) in hydrochloric acid (12M, 30 ml) was added a solution of sodium nitrite (5.0 g, 72.5 mmol) in water (120 ml) at 0 ℃. After stirring for 2 min, the mixture was added to potassium iodide (13.0 g, 78.3 mmol) in water (120 ml), ensuring the temperature did not rise above 10 C. The reaction mixture was stirred at 0 ℃. for 10 min and then at room temperature for 60 h. The mixture was extracted with diethyl ether (2×100 ml), and the combined extracts were washed with brine, dried (MgSO4) and concentrated in vacuo. The residue was purified by column chromatography (silica, 300 g), eluting with diethyl ether/cyclohexane [1:10]. The appropriate fractions were combined and concentrated to give 4-Iodophenylsulphur pentafluoride(16.6 g). |
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| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Bide Pharmatech Ltd.
|
| Telephone: |
400-1647117 13681763483 |
| Website: |
https://www.bidepharm.com/ |
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