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287966-55-6

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287966-55-6 Structure

287966-55-6 Structure
IdentificationBack Directory
[Name]

DMPU-HF Reagent
[CAS]

287966-55-6
[Synonyms]

DMPU-HF Reagent
DMPU-HF Complex
DMPU-HF Reagent (HF 65%)
N,N'-Dimethylpropyleneurea Hydrofluoride
1,3-Dimethylhexahydropyrimidin-2-one hydrofluoride
1,3-Dimethyltetrahydropyrimidin-2(1H)-one Hydrofluoride
Tetrahydro-1,3-dimethyl-2(1H)-pyrimidinone Hydrofluoride
[Molecular Formula]

C6H13FN2O
[MDL Number]

MFCD28385404
[MOL File]

287966-55-6.mol
[Molecular Weight]

148.18
Chemical PropertiesBack Directory
[storage temp. ]

2-8°C
[form ]

liquid
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Skull and Crossbones (GHS06)
GHS05,GHS06
[Signal word ]

Danger
[Hazard statements ]

H300+H310+H330-H314
[Precautionary statements ]

P280-P301+P310+P330-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338
[RIDADR ]

UN 2927 8(6.1) / PGI
[HazardClass ]

6.1/8
[PackingGroup ]

I
Hazard InformationBack Directory
[Uses]

DMPU-HF Reagent is a nucleophilic fluorination reagent that can be used:???????
  • To prepare fluoroalkenes and gem-difluoromethlylene from substituted alkynes in the presence of an Au-JohnPhos complex as a catalyst.??????
  • To synthesize substituted 4-fluorotetrahydropyrans and 4-fluoropiperidines from homoallylic alcohol/amine with aldehyde via fluoro-Prins reaction.???????
  • In the bromofluorination of alkenes in the presence of N-bromosuccinimide to yield corresponding bromofluoro compounds.
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