| Identification | Back Directory | [Name]
BENZOXIMATE | [CAS]
29104-30-1 | [Synonyms]
na-53
NA 53M
ARTABAN
azomate
ACARMATE
CITRAZON
Aazomate
Citrastar
BENZOMATE
BENZOXIMATE
benzoxamate
benzomate (jmaf)
Benzomate standard
benzoximate (bsi,iso)
BENZOXIMATE PESTANAL
BENZOXIMATE PESTANAL(3-CHLORO-A-ETHOXIM&
3-chloro-2,6-dimethoxyl-α-ethoxyimino benzyl benzoate
Ethyl O-benzoyl-3-chloro-2,6-dimethoxybenzohydroxamate
3-CHLORO-ALPHA-ETHOXYIMINO-2,6-DIMETHOXYBENZYLBENZOATE
Benzoic acid 3-chloro-α-ethoxyimino-2,6-dimethoxybenzyl
ETHYL-O-BENZOYL-3-CHLORO-2,6-DIMETHOXY-BENZOHYDROXIMATE
benzoic3-chloro-n-ethoxy-2,6-dimethoxybenzimidicanhydride
o-benzoyl-3-chloro-2,6-dimethoxy-n-ethyl-benzohydroxamicaci
Benzoic acid 3-chloro-α-ethoxyimino-2,6-dimethoxybenzyl ester
benzoicacid,anhydridewith3-chloro-n-ethoxy-2,6-dimethoxybenzimidicacid
Benzoic acid anhydride with 3-chloro-N-ethoxy-2,6-dimethoxybenzenecarboximidic acid | [EINECS(EC#)]
249-439-1 | [Molecular Formula]
C18H18ClNO5 | [MDL Number]
MFCD00055458 | [MOL File]
29104-30-1.mol | [Molecular Weight]
363.79 |
| Chemical Properties | Back Directory | [Melting point ]
73℃ | [Boiling point ]
483.3±55.0 °C(Predicted) | [density ]
1.21 | [storage temp. ]
0-6°C | [solubility ]
DMSO (Slightly), Methanol, (Slightly) | [form ]
Solid | [color ]
White to Off-White | [Water Solubility ]
30.26mg/L(temperature not stated) | [Henry's Law Constant]
1.8×102 mol/(m3Pa) at 25℃, Duchowicz et al. (2020) | [CAS DataBase Reference]
29104-30-1 | [EPA Substance Registry System]
Benzomate (29104-30-1) |
| Hazard Information | Back Directory | [Description]
Benzoximate is an acaricide used to control all stages of spider mites on pome fruit, stone fruit, citrus fruit, vines and ornamentals. It was commercialized in Japan in 1971 but discontinued there in 1998 and is currently registered only in Italy, South Korea, South Africa and Switzerland. | [Chemical Properties]
The pure product is white crystals. mp73°C, vapor pressure <1.33×10-2 Pa (4.53×10-4 Pa at 25°C). Solubility at 20°C: benzene 650 g/L, dimethylformamide 1460 g/L, xylene 710 g/L (1296 g/L), ethanol 70 g/L (93 g/L), hexane 8 g/L, acetone 980 g/L (1440 g/L). It is practically insoluble in water. It is stable to acids but readily decomposes in strong alkaline media, with decomposition or isomerization occurring around 80°C. | [Uses]
Benzoximate is an acaricide that inhibits fruit tree red spider mite Panonychys ulmi (Koch)[1]. | [Production Methods]
While detailed production steps are not widely published for benzoximate due to its obsolete status, its synthesis generally involves constructing a bridged diphenyl structure with functional groups that confer contact and stomach toxicity to mites. The molecule includes a chlorinated aromatic ring and ester functionalities, suggesting that its production likely involves electrophilic aromatic substitution, esterification, and condensation reactions to form the final active compound. | [Mode of action]
The mode of action of benzoximate is not known. Resistance has been reported in citrus red mite, European red mite and twospotted spider mite. | [Toxicity evaluation]
Benzoximate is relatively non-toxic to mammals and fish, but is moderately toxic to predatory mites. | [References]
[1] Kim YJ, et al. Multiple resistance and biochemical mechanisms of pyridaben resistance in Tetranychus urticae (Acari: Tetranychidae). J Econ Entomol. 2006 Jun;99(3):954-8. DOI:10.1603/0022-0493-99.3.954 | [Pesticide Type]
Acaricide; Miticide |
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| Company Name: |
J & K SCIENTIFIC LTD.
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| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
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