| Identification | Back Directory | [Name]
TRIMETHYLSILYLMETHYL ISOCYANIDE | [CAS]
30718-17-3 | [Synonyms]
(ISOCYANOMETHYL)TRIMETHYLSILANE
TRIMETHYLSILYLMETHYL ISOCYANIDE
TRIMETHYLSILYLMETHYL ISOCYANIDE1
Silane, (isocyanoMethyl)triMethyl-
(Trimethylsilyl)methyl isocyanide,(Isocyanomethyl)trimethylsilane | [Molecular Formula]
C5H11NSi | [MDL Number]
MFCD00043056 | [MOL File]
30718-17-3.mol | [Molecular Weight]
113.23 |
| Chemical Properties | Back Directory | [Boiling point ]
52-53 °C35 mm Hg(lit.) | [density ]
0.803 g/mL at 25 °C(lit.) | [refractive index ]
n20/D 1.416(lit.) | [Fp ]
82 °F | [storage temp. ]
-20°C | [form ]
liquid | [BRN ]
3930556 | [InChI]
1S/C5H11NSi/c1-6-5-7(2,3)4/h5H2,2-4H3 | [InChIKey]
OLSTVZKPVGMQKB-UHFFFAOYSA-N | [SMILES]
C[Si](C)(C)C[N+]#[C-] |
| Safety Data | Back Directory | [Hazard Codes ]
F,T | [Risk Statements ]
11-23/24/25 | [Safety Statements ]
16-36/37/39-45 | [RIDADR ]
UN 1993 3/PG 3 | [WGK Germany ]
3 | [F ]
10-21 | [HazardClass ]
3.2 | [PackingGroup ]
III | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Flam. Liq. 2 |
| Hazard Information | Back Directory | [Uses]
(Trimethylsilyl)methyl isocyanide may be used in the preparation of isocyanomethylenetriphenylphosphorane. | [General Description]
Synthesis of (trimethylsilyl)methyl isocyanide and its reaction with protic nucleophiles has been reported. An improved preparation of (trimethylsilyl)methyl isocyanide is reported. Reaction of (trimethylsilyl)methyl isocyanide with (η2-formaldehyde)zirconocene complex is reported to yield insertion products. |
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Sigma-Aldrich
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021-61415566 800-8193336 |
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https://www.sigmaaldrich.cn |
| Company Name: |
Merck KGaA
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21-20338288 |
| Website: |
www.sigmaaldrich.cn |
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