| Identification | Back Directory | [Name]
PHENETHYLZINC BROMIDE | [CAS]
308796-14-7 | [Synonyms]
PHENETHYLZINC BROMIDE
2-Phenylethylzinc bromide
phenethylzinc bromide solution
Phenethylzinc bromide, 0.50 M in THF
PHENETHYLZINC BROMIDE, 0.5M SOLUTION IN
Phenethylzinc bromide solution 0.5 in THF
Phenethylzinc bromide solution 0.5 M in THF
2-Phenylethylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles
2-Phenylethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal&trade
2-Phenylethylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles | [Molecular Formula]
C8H9BrZn | [MDL Number]
MFCD01311437 | [MOL File]
308796-14-7.mol | [Molecular Weight]
250.45 |
| Chemical Properties | Back Directory | [Boiling point ]
65 °C
| [density ]
0.965 g/mL at 25 °C
| [Fp ]
1 °F
| [storage temp. ]
2-8°C | [Water Solubility ]
Reacts with water. | [Sensitive ]
Air Sensitive | [Exposure limits]
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) | [CAS DataBase Reference]
308796-14-7 |
| Hazard Information | Back Directory | [Uses]
Phenethylzinc bromide can be used as a reagent:
- In the transition metal-catalyzed Negishi cross-coupling reaction to prepare aryl or heteroaryl derivatives by reacting with organic halides or triflates via carbon-carbon bond formation.
- To prepare (4-phenyl-1-butyn-1-yl)benzene by reacting with phenylacetylene via palladium-catalyzed cross-coupling reaction.
- To synthesize benzyl substituted thienopyrimidine derivatives.
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