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31469-22-4

31469-22-4 Structure

31469-22-4 Structure
IdentificationBack Directory
[Name]

1,1-BIS(TRIMETHYLSILYLOXY)-1-PROPENE
[CAS]

31469-22-4
[Synonyms]

1,1-BIS(TRIMETHYLSILYLOXY)-1-PROPENE
Methylketene Bis(trimethylsilyl) Acetal
[Molecular Formula]

C9H22O2Si2
[MDL Number]

MFCD01632569
[MOL File]

31469-22-4.mol
[Molecular Weight]

218.44
Chemical PropertiesBack Directory
[Appearance]

clear colorless liquid
[Boiling point ]

60 °C (11 mmHg)
[Fp ]

25 °C
[storage temp. ]

0-6°C
[CAS DataBase Reference]

31469-22-4
Hazard InformationBack Directory
[Chemical Properties]

clear colorless liquid
[Uses]

Used in ?reactive nucleophile in Mukaiyama-type aldol reactions; additions to imines and enones; alkylations with α-halo sulfides; α-hydroxylations.
[Preparation]

1,1-BIS(TRIMETHYLSILYLOXY)-1-PROPENE is prepared by silylation of lithium trialkylsilyl carboxylates or treatment of the dianions of carboxylic acids with Chlorotrimethylsilane at -78 °C (eq 1).
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38-10
[Safety Statements ]

37/39-26-16
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